Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

A. V. Knyazev; Князев А. В.; A. V. Dolganov; Долганов А. В.; L. A. Klimaeva; Климаева Л. А.; S. G. Kostryukov; Кострюков С. Г.; A. Sh. Kozlov; Козлов А. Ш.; A. D. Yudina; Юдина А. Д.; O. V. Tarasova; Тарасова О. В.

doi:10.31857/S0044453723080058

Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

作者: Knyazev A.V.¹, Dolganov A.V.², Klimaeva L.A.², Kostryukov S.G.², Kozlov A.S.², Yudina A.D.², Tarasova O.V.²
隶属关系:
1. Lobachevsky State University
2. Ogarev Mordovian State University
期: 卷 97, 编号 8 (2023)
页面: 1097-1105
栏目: CHEMICAL KINETICS AND CATALYSIS
##submission.dateSubmitted##: 26.02.2025
##submission.datePublished##: 01.08.2023
URL: https://ruspoj.com/0044-4537/article/view/668674
DOI: https://doi.org/10.31857/S0044453723080058
EDN: https://elibrary.ru/QTUEON
ID: 668674

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详细

A study is performed of the electrocatalytic activity of substituted pyridine salts (N-hydro-, N‑methyl-, and N-phenyl-2,4,6-triphenylpyridinium perchlorates) in the electroreduction of carbon dioxide to carbon monoxide. The effect the natures of the substituent and the H+ source have on the efficiency of the process is determined. The main reasons for the occurrence of the electrocatalytic process are identified, and the values of TOF (catalyst speed) and TON (number of revolutions of the catalyst) are calculated. It is shown that the values of TOF and TON fall as the pK of the acid rises.

关键词

electrocatalyst, pyridine, reduction, carbon dioxide

参考

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