Microwave activation in [FeCl3·6H2O–TfOH] - catalysed reaction of binor-s with organic nitriles

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Abstract

An efficient catalytic system, consisting of 20 mol % of FeCl3·6H2O and 20 mol % of trifluoromethanesulfonic acid, for amidation of binor-S in a solution of toluene using organic nitriles under microwave synthesis was developed. Typically the reaction proceeds at 100°C in 15 min.

About the authors

K. S. Frolova

Institute of Petrochemistry and Catalysis, Ufa Federal Researcher Centre of the Russian Academy of Sciences

Email: ksfrolova2022@gmail.com

T. P. Zosim

Institute of Petrochemistry and Catalysis, Ufa Federal Researcher Centre of the Russian Academy of Sciences

A. V. Akhmerova

Institute of Petrochemistry and Catalysis, Ufa Federal Researcher Centre of the Russian Academy of Sciences

I. R. Ramazanov

Institute of Petrochemistry and Catalysis, Ufa Federal Researcher Centre of the Russian Academy of Sciences

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