Modifying Copper with Alumina
during a Mechanically Stimulated Reaction

T. F. Grigoreva; Григорьева Т. Ф.; T. L. Talako; Талако Т. Л.; E. T. Devyatkina; Девяткина Е. Т.; S. V. Vosmerikov; Восмериков С. В.; A. I. Ancharov; Анчаров А. И.; S. V. Tsybulya; Цыбуля С. В.; P. A. Vityaz; Витязь П. А.; N. Z. Lyakhov; Ляхов Н. З.

doi:10.31857/S0015323022600915

Modifying Copper with Alumina during a Mechanically Stimulated Reaction

Authors: Grigoreva T.F.¹, Talako T.L.², Devyatkina E.T.¹, Vosmerikov S.V.¹, Ancharov A.I.¹^,3, Tsybulya S.V.⁴, Vityaz P.A.⁵, Lyakhov N.Z.¹^,6
Affiliations:
1. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences
2. Department of Physical and Technical Sciences, National Academy of Sciences of Belarus, Minsk
3. Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences
4. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
5. Joint Institute of Mechanical Engineering, National Academy of Sciences of Belarus
6. Novosibirsk State University, Faculty of Natural Sciences
Issue: Vol 124, No 1 (2023)
Pages: 78-83
Section: СТРУКТУРА, ФАЗОВЫЕ ПРЕВРАЩЕНИЯ И ДИФФУЗИЯ
URL: https://ruspoj.com/0015-3230/article/view/662803
DOI: https://doi.org/10.31857/S0015323022600915
EDN: https://elibrary.ru/KPAUGG
ID: 662803

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Abstract

IR spectroscopy, electron microscopy, and X-ray diffraction analysis, including the application of synchrotron radiation, have been used to study the mechanochemical reduction of copper oxide with alumi-num at the stoichiometric ratio of the components and in the presence of an excess of oxide-forming metal and aluminum solid solution in copper as well. The possibility is shown of the mechanochemical reduction of copper oxide with aluminum and aluminum solid solution in copper, which is accompanied by the forma-
tion of the Сu/Al2O3 composite structure. To modify copper with alumina, using an aluminum solid solution in copper is preferable.

Keywords

mechanically stimulated reactions, mechanochemical reduction, copper oxide, aluminum solid solution in copper, aluminum, copper

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