Chain Oxidation of Hydroquinone by Water Activated by Pulsed Hot-Plasma Radiation

I. M. Piskarev; Пискарев И. М.

doi:10.31857/S002311932306013X

Chain Oxidation of Hydroquinone by Water Activated by Pulsed Hot-Plasma Radiation

Authors: Piskarev I.M.¹
Affiliations:
1. Skobeltsyn Research Institute of Nuclear Physics, Moscow State University
Issue: Vol 57, No 6 (2023)
Pages: 472-477
Section: PLASMA CHEMISTRY
URL: https://ruspoj.com/0023-1193/article/view/661466
DOI: https://doi.org/10.31857/S002311932306013X
EDN: https://elibrary.ru/SFMXOM
ID: 661466

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Abstract

The interaction of hydroquinone with water activated by hot-plasma pulsed radiation has been studied. In the reactions of hydroquinone with products accumulated in water during irradiation (nitrous and peroxynitrous acids), hydroquinone undergoes chain oxidation to benzoquinone. The mechanism of chain oxidation is analyzed. The decomposition of hydroquinone by corona discharge cold plasma (OH• radicals) was studied. Benzoquinone is not produced by the action of corona discharge; hydroquinone immediately decomposes into smaller molecules. The hydroquinone oxidation process considered can be used to create hydrogen elements based on the hydroquinone ↔ benzoquinone couple.

Keywords

hydroquinone, benzoquinone, plasma-activated water, nitrous acid, oxidation, peroxynitrous acid

About the authors

I. M. Piskarev

Skobeltsyn Research Institute of Nuclear Physics, Moscow State University

Author for correspondence.
Email: i.m.piskarev@gmail.com
Moscow, 119234 Russia

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