Double borates of the BaO–Lu2O3–B2O3 system: crystal chemistry, thermal and optical properties

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Abstract

The paper presents data on synthesis of double borates crystallizing in the BaO–Lu2O3–B2O3 system and Eu3+-activated phosphors based on them as well as on finding of correlations between its chemical composition, crystal structure, thermal and optical properties. Based on results of the investigation of all currently known double Ba–Lu borates, it is shown that search for novel compounds in the system as well as development of optical materials based on them is a promising direction in a field of creating new functional materials for LED applications.

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About the authors

Y. P. Biryukov

B.P. Konstantinov St. Petersburg Nuclear Physics Institute

Email: rimma_bubnova@mail.ru

National Research Centre “Kurchatov Institute” – I.V. Grebenschikov Institute of silicate chemistry

Russian Federation, 199034, St. Petersburg Makarov emb., 2

R. S. Bubnova

B.P. Konstantinov St. Petersburg Nuclear Physics Institute

Author for correspondence.
Email: rimma_bubnova@mail.ru

National Research Centre “Kurchatov Institute” – I.V. Grebenschikov Institute of silicate chemistry

Russian Federation, 199034, St. Petersburg Makarov emb., 2

S. K. Filatov

bSaint Petersburg State University

Email: rimma_bubnova@mail.ru

Institute of Earth Sciences

Russian Federation, 199034 Saint Petersburg, Universitetskaya emb., 7/9

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2. Fig. 1. Double borates crystallizing in the ternary oxide system BaO–Lu2O3–B2O3.

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3. Fig. 2. Crystal structures of double borates of the BaO–Lu2O3–B2O3 system and the main sections of the thermal expansion tensor surface at 25 (solid line) and 800°C (dashed line): Ba6Lu5(BO3)9 (a), Ba2Lu5B5O17 (b), Ba3Lu(BO3)3 (c), Ba3Lu2(B2O5)3 (d), Ba3Lu(B3O6)3 (e)

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