Extraction of actinides and lanthanides from nitric acid solutions with phosphorylated pyrazines

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Abstract

The extraction of U(VI), Th(IV), Am(III), and lanthanides(III) from nitric acid solutions with solutions of phosphorylated pyrazines in organic solvents has been studied. The stoichiometry of the extracted complexes was determined, and the in uence of the structure of the extractant and the concentration of HNO3 in the aqueous phase on the e ciency of the extraction of metal ions into the organic phase was considered. It has been established thatm among the studied compounds, bis(diphenylphosphine)quinoxaline dioxide has the highest extraction ability with respect to actinides and lanthanides in nitric acid media.

About the authors

A. N. Turanov

Osip’yan Institute of Solid State Physics, Russian Academy of Sciences

V. K. Karandashev

Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences

O. I. Artyushin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

E. V. Smirnova

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

G. V. Kostikova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

A. M. Fedoseev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

V. K. Brel

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: v_brel@mail.ru

References

  1. Myasoedov B.F., Kalmykov S.N., Kulyako Yu.M., Vinokurov S.E. // Geochem. Int. 2016. Vol. 54, N 13. P. 1156. https://doi.org/10.1134/S0016702916130115
  2. Leoncini A., Huskens J., Verboom W. // Chem. Soc. Rev. 2017. Vol. 46. P. 7229. https://doi.org/10.1039/C7CS00574A
  3. Wilson A.M., Bailey P.J., Tasker P.A. // Chem. Soc. Rev. 2014. Vol. 43. P. 123. https://doi.org/10.1039/C3CS60275C
  4. Werner E. J., Biros S. M. // Org. Chem. Front. 2019. Vol. 6. P. 2067. https://doi.org/10.1039/C9QO00242A
  5. Аляпышев М.Ю., Бабаин В.А., Устынюк Ю.А. // Успехи химии. 2016. Т. 85. N 9. С. 943
  6. Alyapyshev M Yu., Babain V.A., Ustynyuk Yu.A. // Russ. Chem. Rev. 2016. Vol. 85, N 9. P. 943. https://doi.org/10.1070/RCR4588
  7. Бабаин В.А., Аляпышев М.Ю., Смирнов И.В. // Радиохимия. 2006. Т. 48. С. 369.
  8. Аляпышев М.Ю., Бабаин В.А., Ткаченко Л.И. // Радиохимия. 2014. Т. 56. С. 481.
  9. Ustynyuk Yu.A., Gloriozov I.P., Kalmykov S.N., Mitrofanov A.A., Babain V.A., Alyapyshev M.Yu., Ustynyuk N.A. // Solvent Extr. Ion Exch. 2014. Vol. 32. P. 508. https://doi.org/10.1080/07366299.2014.915666
  10. Alyapyshev M., Babain V., Borisova N., Eliseev I., Kirsanov D., Kostin A., Legin A., Reshetova M., Smirnova Z. // Polyhedron. 2010. Vol. 29. P. 1998. https://doi.org/10.1016/j.poly.2010.03.021
  11. Alyapyshev M., Ashina J., Dar'in D., Kenf E.V., Kirsanov D., Tkachenko L., Legin A., Starova G., Babain V. // RSC Adv. 2016. Vol. 6. P. 68642. https://doi.org/10.1039/C6RA08946A
  12. Matveev P.I., Borisova N.E., Andreadi N.G., Zakirova G.G., Petrov V.G., Belova E.V., Kalmykov S.N., Myasoedov B.F. // DaltonTrans. 2019. Vol. 48. P. 2554. https://doi.org/10.1039/C8DT04729D
  13. Konopkina E.A., Matveev P.I., Huang P.W., Kirsanova A.A., Chernysheva M.G., Sumyanova T.B., Domnikov K.S., Shi W.-Q., Kalmykov S.N., Petrov V.G., Borisova N.E. // Dalton Trans. 2022. Vol. 51. P. 11180. https://doi.org/10.139/d2dt01007k
  14. Konopkina E.A., Matveev P.I., Kharcheva A.V., Sumyanova T.B., Rozdeev A.S., Novichkov D.A., Trigub A.L., Kalle P., Kirsanova A.A., Kalmykov S.N., Petrov V.G., Borisova N.E. // Solvent Extr. Ion Exch. 2023. Vol. 41. P. 627. https://doi.org/10.1080/07366299.2023.2214175
  15. Artyushin O.I., Vologzhanina A.V., Turanov A.N., Karandashev V.K., Brel V.K. // Mendeleev Commun. 2021. Vol. 31. P. 306. https://doi.org/10. 1016/j.mencom.2021.05.009
  16. Туранов А.Н., Карандашев В.К., Артюшин О.И., Костикова Г.В., Федосеев А.М., Брель В.К. // Радиохимия. 2023. Т. 65, № 6. С. 526-531.
  17. Розен А.М., Крупнов Б.В. // Успехи химии. 1996. Т. 65, № 11. С. 1052
  18. Rozen A.M., Krupnov B.V. // Russ. Chem. Rev. 1996. Vol. 65, № 11. P. 973. https://doi.org/10.1070/RC1996v065n11ABEH000241
  19. Беркман З.А., Бертина Л.Э., Кабачник М.И., Коссых В.Г., Медведь Т.Я., Нестерова Н.П., Розен А.М., Юдина К.С. // Радиохимия. 1975. Т. 17, № 2. С. 210.
  20. Розен А.М., Николотова З.И., Карташева Н.А., Медведь Т.Я., Нестерова Н.П., Юдина К.С., Кабачник М.И. // Радиохимия. 1976. Т. 18, № 6. С. 846.
  21. Розен А.М., Николотова З.И., Карташева Н.А. // Радиохимия. 1983. Т. 25, № 5. С. 609.
  22. Туранов А.Н., Карандашев В.К., Артюшин О.И., Костикова Г.В., Федосеев А.М., Брель В.К. // ЖОХ. 2022. Т. 92, № 8. С. 1289
  23. Turanov A.N., Karandashev V.K., Artyushin O.I., Kostikova G.V., Fedoseev A.M., Brel V.K. // Russ. J. Gen. Chem. 2022. Vol. 92. P. 1479. https://doi.org/10.1134/S1070363222080163
  24. Turanov A.N., Karandashev V.K., Artyushin O.I., Brel V.K. // Solvent Extr. Ion Exch. 2020. Vol. 38. P. 166. https://doi.org/10.1080/07366299.2019.1708001
  25. Smirnova E.V., Artyushin O.I., Vologzhanina A.V., Turanov A.N., Karandashev V.K., Brel V.K. // Mendeleev Commun. 2022. Vol. 32. P. 664. https://doi.org/10.1016/j.mencom.2022.09.032
  26. Матросов Е.И., Старикова З.А., Ходак А.А., Нифантьев Э.Е. // ЖНХ. 2003. Т. 48. С. 2008.
  27. Шадрин А.Ю., Смирнов И.В., Киселева Р.Н., Нестерова Н.П., Поликарпов Ю.М., Кабачник М.И. // Радиохимия. 1993. Т. 35, № 1. С. 50.

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