Neptunium(VI) Nitrate Complexes with Urea and Terpyridine Derivatives

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Abstract

Two new complex Np(VI) nitrates with carbamoylurea (biuret) and with a derivative of terpyridine (Ph-Terpy) of the composition [(NpO2)(biuret)(NO3)2] (I) and [H2(Ph-terpy)(NO3)]2[NpO2(NO3)4] (II) have been synthesized and structurally characterized. The coordination environment of Np atoms in compounds are distorted hexagonal bipyramids with “yl” oxygen atoms in apical positions. The equatorial plane of the bipyramid in complex I is formed by oxygen atoms of two bidentate NO 3– anions and an electroneutral ligand. The equatorial plane of the bipyramid in II is formed by oxygen atoms of two bidentate and two monodentate NO 3– anions. The twice protonated Ph-terpy is the basis of the complex cation [H2(Ph-terpy)(NO3)]+.

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About the authors

I. A. Charushnikova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Author for correspondence.
Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

M. S. Grigoriev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

A. M. Fedoseev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

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Supplementary files

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2. Fig. 1. Fragment of structure I. Ellipsoids of temperature shifts are given with a 50% probability. The symmetry operation a is (1–x, y, 3/2–z).

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3. Fig. 2. Fragment of structure II. Ellipsoids of temperature shifts are given with a 50% probability. The symmetry operation a is (1–x, 1–y, 1–z).

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4. Fig. 3. Packing of molecules in structure I.

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5. Fig. 4. Packing of molecules in structure II. Projection in the direction of [001].

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6. Fig. 5. π-π Interaction between [H2Ph-terpy]2+cations in structure II.The hydrogen atoms are not shown.

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