Extraction properties of polyphosphorylated pyridines in nitric acid media

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Abstract

The extraction of U(VI), Th(IV), Am(III), and Eu(III) with solutions of phosphorylated pyridines from nitric acid solutions has been studied. The stoichiometry of the extractable complexes was established. In terms of their extraction ability, these compounds are inferior to bis(diphenylphosphinyl)methane, but they are signi cantly superior to carbamoylmethylphosphine oxides. An increase in the number of phosphine oxide groups in the molecules of phosphorylated pyridines leads to a signi cant decrease in their extraction ability and selectivity in the extraction of Am(III) and Eu(III) from nitric acid solutions.

About the authors

A. N. Turanov

Osipyan Institute of Solid State Physics, Russian Academy of Sciences

V. K. Karandashev

Institute of Microelectronics and High Pure Materials, Russian Academy of Sciences

G. V. Kostikova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

A. M. Fedoseev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

O. I. Artyushin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

V. K. Brel

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: v_brel@mail.ru

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