Preparation of Photoactive TiO2/LTA Zeolite Composites by Solution Technology in Hydrothermal Conditions

N. L. Ovchinnikov; Овчинников Н. Л.; N. M. Vinogradov; Виноградов Н. М.; N. E. Gordina; Гордина Н. Е.; M. F. Butman; Бутман М. Ф.

doi:10.31857/S0044185623700481

Preparation of Photoactive TiO2/LTA Zeolite Composites by Solution Technology in Hydrothermal Conditions

Authors: Ovchinnikov N.L.¹, Vinogradov N.M.¹, Gordina N.E.¹, Butman M.F.¹
Affiliations:
1. Ivanovo State University of Chemical Technology
Issue: Vol 59, No 4 (2023)
Pages: 380-386
Section: ФИЗИКО-ХИМИЧЕСКИЕ ПРОЦЕССЫ НА МЕЖФАЗНЫХ ГРАНИЦАХ
URL: https://ruspoj.com/0044-1856/article/view/663902
DOI: https://doi.org/10.31857/S0044185623700481
EDN: https://elibrary.ru/VSPNDX
ID: 663902

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

For the first time, using solution technology in a reactor under pressure, composites of titanium oxide and LTA zeolite containing 50, 70, and 80% TiO2 were obtained. The materials were characterized by XRD, IR spectroscopy, SEM, energy-dispersive microanalysis, and low-temperature nitrogen adsorption–desorption. The adsorption and photocatalytic properties of the composites were studied using the model dye Rhodamine B as an example. The surface morphology and the textural, adsorption, and photocatalytic properties of the resulting composites, as well as the phase composition of TiO2, largely depend on the degree of coverage of the surface of the zeolite. For 80% TiO2/LTA composites, a degree of coverage close to 100% was observed, and it is for this composition, with a size of TiO2 crystallites of about 11 nm and an anatase/rutile phase ratio of about 0.54, that the highest photocatalytic activity was found.

References

Nakata K., Fujishima A. // J. Photochem. Photobiol., C. 2012. V. 13. P. 169‒189.
Schneider J., Matsuoka M., Takeuchi M. et al. // Chem. Rev. 2014. V. 114. P. 9919.
Dong H., Zeng G., Tang L. et al. // Water Res. 2015. V. 79. P. 128.
Shan A.Y., Ghazi T.I.M., Rashid S.A. // Appl. Catal., A. 2010. V. 389. P. 1.
Zhang W., Zou L., Wang L. // Appl. Catal., A. 2009. V. 371. P. 1.
Wang B., Zhang G., Sun Z., Zheng S. // Powder Technol. 2014. V. 262. P. 1.
Sun Z., Bai C., Zheng S. et al. // Appl. Catal., A. 2013. V. 458. P. 103.
Bahranowski K., Gaweł A., Klimek A. et al. // Appl. Clay Sci. 2017. V. 140. P. 75.
Tokarčíková M., Tokarský J., Čabanová K. et al. // Compos. B: Eng. 2014. V. 67. P. 262.
Sun Z., Li C., Yao G., Zheng S. // Mater. Des. 2016. V. 94. P. 403.
Martins A.C., Cazetta A.L., Pezoti O. et al. // Ceram. Int. 2017. V. 43. P. 4411.
Bouarioua A., Zerdaoui M. // J. Environ. Chem. Eng. 2017. V. 5. P. 1565.
Malakootian M., Pourshaban-Mazandarani M., Hossaini H., Ehrampoush M.H. // Process Saf. Environ. Prot. 2016. V. 104. P. 334.
Huang J., Wang X., Hou Y. et al. // Microporous Mesoporous Mater. 2008. V. 110. P. 543.
Hamandi M., Berhault G., Guillard C., Kochkar H. // Appl. Catal., B. 2017. V. 209. P. 203.
Sohail M., Xue H., Jiao Q. et al. // Mater. Res. Bull. 2017. V. 90. P. 125.
Andronic L., Duta A. // Thin Solid Films. 2007. V. 515. P. 6294.
Kochkina N.E., Agafonov A.A., Vinogradov A.V. et al. // ACS Sustain. Chem. Eng. 2017. V. 5. P. 5148.
Butman M.F., Ovchinnikov N.L., Zinenko N.V. et al. // Catalysts. 2020. V. 10. P. 541.
Butman M.F., Kochkina N.E., Ovchinnikov N.L., Krämer K.W. // Molecules. 2021. V. 26(11). P. 3399.
Butman M.F., Ovchinnikov N.L., Karasev N.S. et al. // Beilstein J. Nanotechnol. 2018. V. 9. P. 364.
Butman M.F., Gushchin A.A., Ovchinnikov N.L. et al. // Catalysts. 2020. V. 10. P. 359.
Zhang G., Song A., Duan Y., Zheng S. // Microporous Mesoporous. Mater. 2018. V. 255. P. 61.
Takeuchi M., Hidaka M., Anpo M. // J. Hazard. Mater. 2012. V. 237–238. P. 133.
Liu S., Lim M., Amal R. // Chem. Eng. Sci. 2014. V. 105. P. 46.
Guesh K., Mayoral Á., Márquez-Álvarez C. et al. // Microporous Mesoporous Mater. 2016. V. 225. P. 88.
Jansson I., Suárez S., Garcia-Garcia F.J., Sánchez B. // Appl. Catal., B. 2015. V. 178. P. 100.
Sun Q., Hu X., Zheng S. et al. // Powder Technol. 2015. V. 274. P. 88.
Gomez S., Marchena C.L., Pizzio L., Pierella L. // J. Hazard Mater. 2013. V. 258–259. P. 19.
Shankar M.V., Anandan S., Venkatachalam N. et al. // Chemosphere. 2006. V. 63(6). P. 1014.
Tehubijuluw H., Subagyo R., Yulita M.F. et al. // Environ. Sci. Pollut. Res. 2021. V. 28. P. 37354.
Kamegawa T., Kido R., Yamahana D., Yamashita H. // Microporous and Mesoporous Mater. 2013. V. 165. P. 142.
Liu X., Liu Y., Lu S. et al. // Chem. Eng. J. 2018. V. 350. P. 131.
Al-Harbi L.M., Kosa S.A., Abd El Maksod I.H., Hegazy E.Z. // J. Nanomater. 2015. V. 2015. Article ID 565849.
Lv Z., Tao Y., Zhang W. // Mech. and Catal. 2021. V. 133. P. 531.
Rahman A., Nurjayadi M., Wartilah R. et al. // Int. J. Technol. 2018. V. 6. P. 1159.
Li F., Jiang Y., Yu L. et al. // Appl. Surf. Sci. 2005. V. 252. P. 1410.
Chen H., Matsumoto A., Nishimiya N., Tsutsumi K. // Colloids Surf. A: Physicochem. Eng. Asp. 1999. V. 157. P. 295.
Kuwahara Y., Aoyama J., Miyakubo K. et al. // J. Catal. 2012. V. 285. P. 223.
Fukugaichi S., Henmi T., Matsue N. // Catal. Lett. 2013. V. 143. P. 1255.
Li Y., Li S.G., Wang J. et al. // Russ. J. Phys. Chem. A. 2014. V. 88. P. 2471.
Diban N., Pacuła A., Kumakiri I. et al. // Catalysts. 2021. V. 11. P. 1367.
Zheng H., Shi J., Hu B.Z. et al. // Key Eng. Mater. 2007. V. 334–335. P. 1029.
Alakhras F., Alhajri E., Haounati R. et al. // Surf. Interfaces. 2020. V. 20. P. 100611.
Nagarjuna R., Roy S., Ganesan R. // Microporous and Mesoporous Mater. 2015. V. 211. P. 1.
Badvi K., Javanbakht V. // J. Clean. Prod. 2021. V. 280. P. 124518.
Subagyo R., Tehubijuluw H., Utomo W.P. et al. // Arab. J. Chem. 2022. V. 15. P. 103754.
Znad H, Abbas K., Hena S., Awual Md.R. // J. Environ. Chem. Eng. 2018. V. 6. P. 218.
Mahalakshmi M., Vishnu Priya S., Arabindoo B. et al. // J. Hazard. Mater. 2009. V. 161(1). P. 336.
Rathi A., Barman S., Basu S., Arya R.K. // Chemosphere. 2022. V. 288. P. 132609.
Baerlocher Ch., McCusker L.B., Olson D.H. Atlas of Zeolite Framework Types, 6th ed. / Elsevier Science: Amsterdam, 2007. P. 404.
Гордина Н.Е., Прокофьев В.Ю., Борисова Т.Н., Елизарова А.М. // Изв. вузов. Химия и хим. технология. 2019. Т. 62. Вып. 7. С. 99.
Bernier A.; Admaiai L.F., Grange P. // Appl. Catal. 1991. V. 77. P. 269.
García-Soto A.R., Rodríguez-Niño G., Trujillo C.A. // Ing. e Investig. 2013. V. 33. P. 22.
Moma J., Baloyi J. Modified Titanium Dioxide for Photocatalytic Applications. In: Khan, S.B., Akhtar, K., editors. Photocatalysts – Applications and Attributes [Internet]. London: IntechOpen; 2018 [cited 2022 Jun 20]. Available from: https://www.intechopen.com/chapters/62303 https://doi.org/10.5772/intechopen.79374
da Silva Filho S.H., Vinaches P., Silva H.L.G. et al. // SN Appl. Sci. 2020. V. 2. P. 344.
Bouzakher-Ghomrasni N., Tache O., Leroy J. et al. Dimensional measurement of TiO_2 (Nano) particles by SAXS and SEM in powder form. Talanta, Elsevier, 2021. In press, 234, P.122619.