Studying the Composition of Cluster Ions by Matrix- and Surface-Activated Laser Desorption/Ionization in Samples Obtained from Solutions of Sodium Stannate and Tin(II) Chloride

D. O. Sukhorukov; Сухоруков Д. О.; I. S. Pytskii; Пыцкий И. С.; A. K. Buryak; Буряк А. К.; A. I. Revel’skii; Ревельский А. И.; I. A. Revel’skii; Ревельский И. А.

doi:10.31857/S0044185623700766

Studying the Composition of Cluster Ions by Matrix- and Surface-Activated Laser Desorption/Ionization in Samples Obtained from Solutions of Sodium Stannate and Tin(II) Chloride

Authors: Sukhorukov D.O.¹, Pytskii I.S.¹, Buryak A.K.¹, Revel’skii A.I.², Revel’skii I.A.²
Affiliations:
1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
2. Faculty of Chemistry, Moscow State University
Issue: Vol 59, No 6 (2023)
Pages: 612-620
Section: МЕТОДЫ ИЗУЧЕНИЯ ФИЗИКО-ХИМИЧЕСКИХ СИСТЕМ
URL: https://ruspoj.com/0044-1856/article/view/663947
DOI: https://doi.org/10.31857/S0044185623700766
EDN: https://elibrary.ru/GHYFAZ
ID: 663947

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Abstract

The purpose of this work was to study the composition of cluster ions in samples containing sodium stannate and tin(II) chloride. It has been shown that the composition of mass spectra is influenced by such parameters as the laser radiation energy and the substance content in the sample being studied. Conditions for preparing samples and recording mass spectra using these parameters were optimized. Presumptive identification of peaks in the recorded mass spectra was carried out. It has been shown that many of the ion peaks observed in the mass spectra may correspond to clusters containing tin. In the mass spectra of sodium stannate, ions of the general composition SnxOyNazHm were detected, in which the number of tin atoms reaches eight, and the maximum ion mass-to-charge ratio (m/z) is 1100. In the mass spectra of tin(II) chloride, there are ions of the general composition SnxOyHmClp and SnxCly, where the number of tin atoms reaches 4, and the highest m/z value is 1000.

Keywords

mass spectrometry, matrix-assisted laser desorption/ionization, tin, sodium stannate, tin(II), chloride, solution, cluster, cluster ion, matrix, laser

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