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Growth Conditions and the Structural and Magnetic Properties of Cu2MBO5 (M = Cr, Fe, Mn) Oxyborates with a Ludwigite Structure
- Authors: Moshkina E.M1, Bel'skaya N.A2, Molokeev M.S1,3, Bovina A.F1, Shabanova K.A4, Kokh D.5,4, Seretkin Y.V6,7, Velikanov D.A1, Eremin E.V1, Krylov A.S.1, Bezmaternykh L.N1
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Affiliations:
- Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences
- Ioffe Institute, Russian Academy of Sciences
- Far-Eastern State Transport University
- Russia Federal Research Center, Siberian Branch, Russian Academy of Sciences
- Siberian Federal University
- Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 163, No 1 (2023)
- Pages: 24-34
- Section: Articles
- URL: https://ruspoj.com/0044-4510/article/view/653573
- DOI: https://doi.org/10.31857/S0044451023010030
- EDN: https://elibrary.ru/NMXIAV
- ID: 653573
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Abstract
Copper oxyborate single crystals with a ludwigite structure, Cu2MBO5 (M = Cr, Fe, Mn), containing different substitutes in the trivalent subsystem have been grown from Bi2O3–MoO3–Na2O–B2O3 fluxes. The structural properties of grown compounds have been compared in detail using X-ray diffraction and Raman spectroscopy methods. In addition, these methods have been used to determine the degree of cationic ordering in these ludwigites. The temperature and field dependences of the Cu2MBO5 (M = Cr, Fe, Mn) ludwigite magnetization are presented.
About the authors
E. M Moshkina
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences
Email: ekoles@iph.krasn.ru
N. A Bel'skaya
Ioffe Institute, Russian Academy of Sciences
Email: jetp@kapitza.ras.ru
M. S Molokeev
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences; Far-Eastern State Transport University
Email: jetp@kapitza.ras.ru
A. F Bovina
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences
Email: jetp@kapitza.ras.ru
K. A Shabanova
Russia Federal Research Center, Siberian Branch, Russian Academy of Sciences
Email: jetp@kapitza.ras.ru
D. Kokh
Siberian Federal University; Russia Federal Research Center, Siberian Branch, Russian Academy of Sciences
Email: jetp@kapitza.ras.ru
Yu. V Seretkin
Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: jetp@kapitza.ras.ru
D. A Velikanov
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences
Email: jetp@kapitza.ras.ru
E. V Eremin
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences
Email: jetp@kapitza.ras.ru
A. S. Krylov
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences
Email: jetp@kapitza.ras.ru
L. N Bezmaternykh
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: jetp@kapitza.ras.ru
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