Preparation of Polymetal Powder Systems Fe–Ni–Co–Al in Aqueous Solutions and Their Physical Characteristics

A. F. Dresvyannikov; Дресвянников А. Ф.; M. E. Kolpakov; Колпаков М. Е.; E. A. Ermolaeva; Ермолаева Е. А.

doi:10.31857/S0044453723100072

Preparation of Polymetal Powder Systems Fe–Ni–Co–Al in Aqueous Solutions and Their Physical Characteristics

Authors: Dresvyannikov A.F.¹, Kolpakov M.E.¹, Ermolaeva E.A.¹
Affiliations:
1. Kazan National Research Technological University
Issue: Vol 97, No 10 (2023)
Pages: 1421-1429
Section: ФИЗИЧЕСКАЯ ХИМИЯ РАСТВОРОВ
Submitted: 26.02.2025
Published: 01.10.2023
URL: https://ruspoj.com/0044-4537/article/view/668640
DOI: https://doi.org/10.31857/S0044453723100072
EDN: https://elibrary.ru/TQMNAS
ID: 668640

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Abstract

The possibility of preparation of a polymetallic dispersed Fe–Ni–Co–Al system in aqueous solutions by a redox process between iron(III), nickel(II), cobalt(II) ions and aluminum microparticles in aqueous solutions is shown. In this case, a structure is formed in the aqueous solution, which, from the standpoint of the phase composition, is a mechanical mixture of elemental metals. It has been found that the synthesized Fe–Ni–Co–Al system consists of metallic aluminum particles coated with elemental metals (iron, nickel, and cobalt) with a minimum content of the oxide phase. Additional HF modification of the studied sample of the polymetallic system in low pressure inductive discharge plasma leads to the formation of a number of intermetallic compounds, mainly CoFe (~60%) and FeNi (~15%), and also ensures particle spheroidization. The resulting intermetallic powder composition is potentially suitable for use in additive manufacturing technologies.

Keywords

aluminum, iron family metals, plasma, intermetallics

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