Mechanism of the Thermolysis of Magnesium Perylenetetracarboxylates

S. A. Naifert; Найферт С. А.; D. A. Zherebtsov; Жеребцов Д. А.; D. A. Uchaev; Учаев Д. А.; R. S. Morozov; Морозов Р. С.; K. R. Smolyakova; Смолякова К. Р.; E. M. Orlova; Орлова Е. М.; A. A. Pan’kova; Панькова А. А.; A. L. Sharova; Шарова А. Л.

doi:10.31857/S0044453723060201

Mechanism of the Thermolysis of Magnesium Perylenetetracarboxylates

Authors: Naifert S.A.¹, Zherebtsov D.A.¹, Uchaev D.A.¹, Morozov R.S.¹, Smolyakova K.R.¹, Orlova E.M.¹, Pan’kova A.A.¹, Sharova A.L.¹
Affiliations:
1. South Ural State University
Issue: Vol 97, No 6 (2023)
Pages: 850-859
Section: ФИЗИЧЕСКАЯ ХИМИЯ НАНОКЛАСТЕРОВ, СУПРАМОЛЕКУЛЯРНЫХ СТРУКТУР И НАНОМАТЕРИАЛОВ
Submitted: 27.02.2025
Published: 01.06.2023
URL: https://ruspoj.com/0044-4537/article/view/668723
DOI: https://doi.org/10.31857/S0044453723060201
EDN: https://elibrary.ru/KCONVW
ID: 668723

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Black-red and orange magnesium perylene-3,4,9,10-tetracarboxylate species are synthesized in the ion-exchange reaction at room temperature and by boiling an aqueous solution, respectively. Upon heating the two species to 500°C in argon, they reversibly lose 19–27 wt % of their crystallization water, and the products become black. X-ray diffraction analysis results show the preservation of the layered structure upon heating, which is confirmed via transmission electron microscopy. Exposure to a humid atmosphere rehydrates and restores the original structure. Thermolysis to 1000°С in argon produces a composite of MgO nanoparticles in a porous glassy carbon matrix. The stability of perylenetetracarboxylates up to 500°C makes them a promising candidate for synthesizing metal–organic frameworks.

Keywords

carbon, perylenetetracarboxylates, metal–organic frameworks, thermal analysis

References

Кустов Л.М., Куделин А.И., Исаева В.И. // Журн. физ. химии. 2019. Т. 93. № 12. С. 1763. https://doi.org/10.1134/S004445371912015X
Zulys A., Asrianti D., Gunlazuardi J. // The 8th International Conference of the Indonesian Chemical Society (ICICS) 2019. AIP Conf. Proc. 2019. V. 2243 (1): 020035. https://doi.org/10.1063/5.0005001.
Sondermann L., Jiang W., Shviro M. et al. // Molecules. 2022. V. 27. P. 1241. https://doi.org/10.3390/molecules27041241
Sun X., Yu Q., Zhang F. et al. // Catal. Sci. Technol. 2016. V. 6. P. 3840–3844. https://doi.org/10.1039/C5CY01716E
Adawiah A., Yudhi M.D.L., Zulys A. // J. Kimia Valensi. 2021. V. 7 (2). P. 129. https://doi.org/10.15408/jkv.v7i2.22267
Mo F., Han Q., Chen M. et al. // Nanoscale. 2021. V. 13. P. 16244. https://doi.org/10.1039/D1NR03300J
Wu H.B., Lou X.W. // Sci. Adv. 2017. V. 3. P. 9252. https://doi.org/10.1126/sciadv.aap9252
Полозов М.А., Найферт С.А., Полозова В.В. и др. // Вестн. Южно-Уральского гос. ун-та. Серия: Химия. 2019. Т. 11. № 2. С. 39. https://doi.org/10.14529/chem190204
Сактхидхаран Ч.П., Полозов М.А., Полозова В.В. и др. // Журн. физ. химии. 2020. Т. 94. № 7. С. 981. https://doi.org/10.31857/S0044453720070250
Толстогузов Д.С., Жеребцов Д.А., Груба О.Н. и др. // Там же. 2022. Т. 96. № 1. С. 101. https://doi.org/10.31857/S0044453722010241
Pierson H.O. Handbook of Carbon, Graphite, Diamond and Fullerene: Properties, Processing and Applications. New Jersey: Noyes Publications, 1993. 399 c.
Жеребцов Д.А., Найферт С.А., Полозов М.А. и др. // Журн. физ. химии. 2021. Т. 95. № 12. С. 1882. https://doi.org/10.31857/S0044453721120232
Majumder M., Sheath P., Mardel J.I. et al. // Chem. Mater. 2012. V. 24. P. 4647. https://doi.org/10.1021/cm301726k
Zhao J., Li M., Sun J. et al. // Chem. Eur. J. 2012. V. 18. P. 3163. https://doi.org/10.1002/chem.201103415
Sikdar N., Dutta D., Haldar R. et al. // J. Phys. Chem. C. 2016. V. 120. 25. P. 13622. https://doi.org/10.1021/acs.jpcc.6b04347
Huang M., Schilde U., Kumke M. et al. // J. Am. Chem. Soc. 2010. V. 132. 11. P. 3700–3707. https://doi.org/10.1021/ja906667x
Ronfeldt P., Reinsch H., Poschmann M.P.M. et al. // Cryst. Growth Des. 2020. V. 20. 7. P. 4686–4694. https://doi.org/10.1021/acs.cgd.0c00478
Джардималиева Г.И., Помогайло А.Д. Мономерные и полимерные карбоксилаты металлов. М.: Физматлит, 2009. 400 с.