Equation of State of an Infinitely Dilute Solution of Argon in Water

A. A. Novikov; Новиков А. А.

doi:10.31857/S0044453723050205

Equation of State of an Infinitely Dilute Solution of Argon in Water

Authors: Novikov A.A.¹
Affiliations:
1. Faculty of Chemistry, Moscow State University
Issue: Vol 97, No 5 (2023)
Pages: 662-672
Section: ФИЗИЧЕСКАЯ ХИМИЯ РАСТВОРОВ
Submitted: 27.02.2025
Published: 01.05.2023
URL: https://ruspoj.com/0044-4537/article/view/668739
DOI: https://doi.org/10.31857/S0044453723050205
EDN: https://elibrary.ru/HLUKRS
ID: 668739

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Abstract

A new equation of state is proposed for a solution of gas at infinite dilution, based on considering the interaction between a gas and a solvent at the microscopic level. It is used to describe the properties of an infinitely dilute aqueous solution of argon in a wide range of temperatures and pressures, including the supercritical region of water. It is shown that the resulting equation is capable of predicting the properties of an aqueous solution of an inert gas with high accuracy, based on a limited set of data at moderate temperatures.

Keywords

equation of state, thermodynamic model, reference level, solution at infinite dilution, argon, water

About the authors

A. A. Novikov

Faculty of Chemistry, Moscow State University

Author for correspondence.
Email: novikov.chem@gmail.com
119991, Moscow, Russia

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