Obtaining Methanol from CO2 on Cu–Zn/Al2O3 and Cu–Zn/SiO2 Catalysts: Effect of the Support and Conditions of the Reaction

K. O. Kim; Ким К. О.; A. A. Shesterkina; Шестеркина А. А.; M. A. Tedeeva; Тедеева М. А.; K. E. Kartavova; Картавова К. Е.; P. V. Pribytkov; Прибытков П. В.; S. F. Dunaev; Дунаев С. Ф.; A. L. Kustov; Кустов А. Л.

doi:10.31857/S0044453723040179

Obtaining Methanol from CO2 on Cu–Zn/Al2O3 and Cu–Zn/SiO2 Catalysts: Effect of the Support and Conditions of the Reaction

Authors: Kim K.O.¹, Shesterkina A.A.¹^,2, Tedeeva M.A.¹, Kartavova K.E.¹, Pribytkov P.V.¹, Dunaev S.F.¹, Kustov A.L.¹^,2
Affiliations:
1. Faculty of Chemistry, Moscow State University
2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Issue: Vol 97, No 4 (2023)
Pages: 495-499
Section: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
Submitted: 27.02.2025
Published: 01.04.2023
URL: https://ruspoj.com/0044-4537/article/view/668755
DOI: https://doi.org/10.31857/S0044453723040179
EDN: https://elibrary.ru/TGBKPM
ID: 668755

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Abstract

A study is performed of the catalytic properties of Cu–Zn catalysts on Al2O3 and SiO2 supports (Acros) in the reaction of CO2 hydrogenation to obtain methanol. A sample of 30Cu15Zn/Al2O3 displays great selectivity toward methanol. A sample of 30Cu15Zn/SiO2 has the highest methanol performance. The methanol performance of a sample of 10Cu5Zn/Al2O3 is doubled when the pressure is raised from 10 to 30 atm, and a 94% increase in selectivity is observed. A sample of catalyst 10Cu5Zn/SiO2 does not lose its activity after 10 h of a catalytic reaction, and its methanol performance grows with repeated use

Keywords

bimetallic catalysts, copper oxide, zinc oxide, silica gel, aluminum oxide, carbon dioxide hydrogenation, methanol production, utilization of carbon dioxide

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