Thermodynamics of the Formation of Intermediate Complexes in the Oxidation of Citric Acid with Cerium(IV) and the Kinetics of Their Intramolecular Redox Decomposition

O. O. Voskresenskaya; Воскресенская О. О.; N. A. Skorik; Скорик Н. А.

doi:10.31857/S0044453723040337

Thermodynamics of the Formation of Intermediate Complexes in the Oxidation of Citric Acid with Cerium(IV) and the Kinetics of Their Intramolecular Redox Decomposition

Authors: Voskresenskaya O.O.¹, Skorik N.A.²
Affiliations:
1. Joint Institute for Nuclear Research
2. Tomsk State University
Issue: Vol 97, No 4 (2023)
Pages: 517-526
Section: ФИЗИЧЕСКАЯ ХИМИЯ РАСТВОРОВ
Submitted: 27.02.2025
Published: 01.04.2023
URL: https://ruspoj.com/0044-4537/article/view/668759
DOI: https://doi.org/10.31857/S0044453723040337
EDN: https://elibrary.ru/TJMWUQ
ID: 668759

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Abstract

The thermodynamic and kinetic characteristics of cerium(IV)–citrate complexes formed at the first step of oxidation of citric acid with cerium(IV) are studied via spectrophotometric, pH-metric, and kinetic means at an ionic strength of I = 2 in the 1–3 range of the pH of a sulfuric acid medium at T = 290.15–303.15 K. The composition of these complexes, the species of the organic ligand in them, the thermodynamic parameters of their formation, and the kinetic parameters of the intracomplex redox decomposition are determined. The most likely scheme of the initial steps of the redox process in the system are considered, and its rate law and the related mechanism of the reaction are established. Results are compared to ones from studies of other cerium(IV) systems with hydroxy and dicarboxylic acids.

Keywords

thermodynamics, kinetics, solutions, complexes, cerium, hydroxy acids

About the authors

O. O. Voskresenskaya

Joint Institute for Nuclear Research

Email: voskr@jinr.ru
141980, Dubna, Moscow oblast, Russia

N. A. Skorik

Tomsk State University

Author for correspondence.
Email: voskr@jinr.ru
634050, Tomsk, Russia

References

Zhang J., Wenzel M., Schnaars K. et al. // Dalton Trans. 2021. V. 50. P. 3550.https://doi.org/10.1039/D1DT00365H
Jacobsen J., Wegner L., Reinsch H. et al. // Dalton Trans. 2020. V. 49. P. 11396. https://doi.org/10.1039/D0DT02455D
Kozlova T.O., Baranchikov A.E., Ivanov V.K. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1761. https://doi.org/10.1134/S003602362112010X
Lopatin S.I., Shugurov S.M., Kurapova O.Y. // Russ. J. Gen. Chem. 2021. V. 91. P. 2008. https://doi.org/10.1134/S1070363221100121
Issa G., Dimitrov M., Ivanova R. et al. // Reac. Kinet. Mech. Cat. 2022. V. 135. № 2–3. P. 105. https://doi.org/10.1007/s11144-021-02135-0
Dalanta F., Kusworo T.D. // Chem. Eng. J. 2022. V. 434. Article ID 134687. https://doi.org/10.1016/j.cej.2022.134687
Colliard I., Nyman M. // Angew. Chem. Int. Ed. 2021. V. 60. № 13. P. 7308. https://doi.org/10.1002/anie.202016522
Wadekar K., Aswaleb S., Yatham V.R. // Org. Biomol. Chem. 2020. V. 18. P. 983. https://doi.org/10.1039/C9OB02676B
Yedase G.S., Kumar S., Stahl J. et al. // Beilstein J. Org. Chem. 2021. V. 17. P. 1727. https://doi.org/10.3762/bjoc.17.121
Ragukumar G., Nethaji O. // Indian J. Natur. Sci. 2021. V. 12. № 69. P. 36350.
Ciriminna R., Meneguzzo F., Delisi R. et al. // Chem. Centr. J. 2017. V. 11. P. 22. https://doi.org/10.1186/s13065-017-0251-y
Duangsa K., Tangtrakarn A., Mongkolkachit C. et al. // Adv. Mater. Sci. Eng. 2021. Article ID 5592437. https://doi.org/10.1155/2021/5592437
Bao Y., Ma J., Pan Ch. et al. // Chemosphere. 2020. V. 240. P. 124897. https://doi.org/10.1016/j.chemosphere.2019.124897
Zhang S.H., Yang B., Li M.D. et al. // Key Eng. Mater. 2019. V. 814. P. 144. https://doi.org/10.4028/www.scientific.net/KEM.814.144
Wu Y., Li H., Bian X. et al. // Materials. 2021. V. 14. № 17. P. 4963.
Таран В.Г., Боровская Л.В., Мазуренко Е.А. // Науч. обозр. (РЖ). 2019. № 2. С. 24.
Васильев В.П. Аналитическая химия. Часть 1. Гравиметрический и титриметрический методы анализа. М.: Высш. школа, 1989. 320 с.
Marunkić D., Pejić J., Jegdicć B. et al. // Materials and Corrosion. 2022. V. 73. № 6. P. 950.
Zherbakov A.B., Zholobak N.M., Ivanov V.K. // Cerium Oxide (Ce): Synthesis, Properties and Applications / Ed.by S. Scire, M. Palmisano. Amsterdam: Elsevier, 2019. 402 p.
Hancock M.L., Yokel R.A., Beck M.J. et al. // Appl. Surf. Sci. 2021. V. 535. Article ID https://doi.org/10.1016/j.apsusc.2020.147681
Toxicological Reviev of Cerium Oxide and Cerium Compounds (CAS № 1306-383). Washington: U.S. Enviromental Protection Agency, 2009.
Cassani A., Monteverde A., Piumetti M. // J. Math. Chem. 2021. V. 59. P. 792.
Воскресенская О.О., Скорик Н.А. // Журн. физ. химии. 2015. Т. 89. № 10. С. 1619; Voskresenskaya O.O., Skorik N.A. // Russ. J. Phys. Chem. 2015. V. 89. № 10. P. 1821.
Čupić Ž., Lente G. // React. Kinet. Mech. Catal. 2022. V. 135. № 3. P. 1137.
Muzika F., Górecki J. // Ibid. 2022. V. 135. № 3. P. 1187.
Kasperek G.T., Bruice T.C. // Inorg. Chem. 1971. V. 10. P. 382.
Rustici M., Lombardo R., Mangone M. et al. // Faraday Disc. 2001. V. 120. P. 47.
Воскресенская О.О., Скорик Н.А., Южакова Ю.В. // Журн. физ. химии. 2017. Т. 91. № 4. С. 601.
Nebel D., Urban G. // Z. Phys. Chem. (DDR). 1966. V. 233. P. 73.
Печурова Н.И., Вахрамова Г.П., Спицын В.И. // Журн. неорган. химии. 1974. Т. 19. № 8. С. 2074.
Воскресенская О.О., Скорик Н.А. // Журн. физ. химии. 2009. Т. 83. № 6. С. 1079.
Sengupta K.K. // Bull. Chem. Soc. Japan. 1969. № 2. P. 298.
Tripathy S.N., Prasad R.K. // Ind. J. Chem. A. 1980. V. 19. P. 214.
Datt N., Nagori R., Mehrotra R. // Can. J. Chem. A. 1986. V. 64. P. 19.
Felmy A.R., Cho H., Dixon D.A. et al. // Radiochim. Acta. 2006. V. 94. № 4. P. 205.
Thuéry P. // Cryst. Eng. Com. 2008. V. 10. № 2–3. P. 79.
Добрынина Н.А., Мартыненко Л.И. // Проблемы современной химии координационных соединений / Под ред. К.А. Буркова. Л.: Изд-во ЛГУ, 1989. С. 98.
Martell A.E., Smith R.M., Motekaitis R.J. NIST Critically Selected Stability Constants of Metal Complexes. Database: Version 8.0. National Inst of Standards and Technology, Gaithersburg, 2004.
Binnemans K. // Handbook on the Physics and Chemistry of Rare Earts, V. 36. / Ed.by K.A. Gschneidner. North-Holland: Elsevier, 2006. P. 281.
Singh R.S., Jha P.N., Prasad R.K. // Proc. Nation. Sci. 1987. V. LVII. № III. P. 272.
Hardwich T.G., Robertson E. // Can. J. Chem. A. 1955. V. 29. P. 818.
Атрошенко Ю.К. Оптимизация статических и динамических режимов. Томск: Изд-во ТПУ, 2019. С. 2.
Воскресенская О.О., Скорик Н.А. // Журн. прикл. химии. 2002. Т. 75. № 6. С. 886; Voskresenskaya O.O., Skorik N.A. // Russ. J. Appl. Chem. 2002. V. 75. № 6. P. 866.
Воскресенская О.О., Скорик Н.А., Соковикова Н.И. // Журн. неорган. химии. 2019. Т. 64. № 4. С. 1095.
Яцимирский К.Б., Костромина Н.А., Шека З.А. и др. Химия комплексных соединений редкоземельных элементов. Киев: Наукова думка, 1966. 493 с.
Casari B.M., Lander V. // Acta Crystallogr. C. 2007. V. 63. № 4. P. i25.
Скорик Н.А., Чернов Е.Б. Расчеты с использованием персональных компьютеров в химии комплексных соединений. Томск: Изд-во ТГУ, 2009. 90 с.