New Barium Fluorosuccinato and Fluoroglutarato Uranylates

V. N. Serezhkin; Сережкин В. Н.; M. S. Grigoriev; Григорьев М. С.; M. V. Sukacheva; Сукачева М. В.; L. B. Serezhkina; Сережкина Л. Б.

doi:10.31857/S0044453723040283

New Barium Fluorosuccinato and Fluoroglutarato Uranylates

Authors: Serezhkin V.N.¹, Grigoriev M.S.², Sukacheva M.V.¹, Serezhkina L.B.¹
Affiliations:
1. Samara National Research University
2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Issue: Vol 97, No 4 (2023)
Pages: 535-542
Section: СТРОЕНИЕ ВЕЩЕСТВА И КВАНТОВАЯ ХИМИЯ
Submitted: 27.02.2025
Published: 01.04.2023
URL: https://ruspoj.com/0044-4537/article/view/668772
DOI: https://doi.org/10.31857/S0044453723040283
EDN: https://elibrary.ru/TIMCCR
ID: 668772

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Abstract

Two new coordination polymers: Ba2[(UO2)3(suc)3F4]⋅5H2O (I) and Ba[(UO2)2(glt)2(Hglt)F]⋅8H2O (II), where suc is C4H4O2−442− (succinate ion) and glt is C5H6O2−442− (glutarate ion), were synthesized, and their structure was studied. The uranium-containing structural units of crystals I are the [(UO2)3(C4H4O4)3F4]4– layers belonging to the crystal-chemical group A3(Q02)3M22M22M12M21 of uranyl complexes, where A = UO2+2UO22+, Q02 = C4H4O2−442−, М1 and М2 = F–. Structure II contains the uranium-containing 3D complex [(UO2)2(C5H6O4)2(C5H7O4)F]2–, which corresponds to the crystal-chemical formula A2(Q02)2B01M2, where A = UO2+2UO22+, Q02 = C5H6O2−442−, B01 = C5H7O−44−, and М2 = F–.

Keywords

uranyl complexes, succinate ions, glutarate ions, crystal structure, Voronoi–Dirichlet polyhedra

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