Finsler–Lagrange Kinetic Model of the Structurization of a Langmuir Monolayer

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Abstract

A model is proposed for the synthesis of nanocyclic iron coordination complexes on the surface of an aqueous solution of ferric iron salts during a two-dimensional solid (S)–liquid expanded (L') phase transition of first order. Electrocapillary effects in the nucleation kinetics for such Langmuir monolayers are studied in the context of the Finsler–Lagrangian formalism. It is shown that under conditions of rapid compression, an additional local minimum appears in the surface tension potential of the monolayer. This minimum causes supersaturation of the phase and the formation of nuclei (domains) of the crystalline phase with sizes considerably exceeding the critical one, resulting in a plateau on the compression isotherm and the formation of a multidomain monolayer structure. It is established that since the effective charge of hydrated ferrous iron complexes is greater than that of ferric iron complexes, electrocapillary phenomena at the phase boundary lead to the formation of domains of high-spin octahedral ferrous iron complexes with dithionylpyrrole oligomers.

About the authors

N. G. Krylova

Belarusian State Agrarian Technical University

Email: nina-kr@tut.by
220023, Minsk, Belarus

G. V. Grushevskaya

Belarusian State University

Author for correspondence.
Email: grushevskaja@bsu.by
220030, Minsk, Belarus

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