Complexes of Zinc Nitrate and Lanthanide Nitrates with Urea in the 1 : 2 Ratio

I. A. Karavaev; Караваев И. А.; E. V. Savinkina; Савинкина Е. В.; S. S. Ponkrashina; Понкрашина С. С.; M. S. Grigor’ev; Григорьев М. С.

doi:10.31857/S0044457X22601948

Complexes of Zinc Nitrate and Lanthanide Nitrates with Urea in the 1 : 2 Ratio

Authors: Karavaev I.A.¹, Savinkina E.V.¹, Ponkrashina S.S.¹, Grigor’ev M.S.²
Affiliations:
1. Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University
2. Frumkin Institute of Physical Chemistry and Electrochemistry
Issue: Vol 68, No 7 (2023)
Pages: 923-929
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://ruspoj.com/0044-457X/article/view/665225
DOI: https://doi.org/10.31857/S0044457X22601948
EDN: https://elibrary.ru/RHLQQD
ID: 665225

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract

Coordination compounds [Zn(H2O)4(Ur)2](NO3)2, [M(H2O)2(Ur)2(NO3)3] (M = Ce, Nd), and [Dy(H2O)(Ur)2(NO3)3] have been synthesized by the reaction of nitrates of zinc or rare earth elements with urea (Ur) in an aqueous solution. Their composition has been determined and structural features have been established using elemental analysis, IR spectroscopy, and X-ray diffraction analysis. For the zinc complex, a polymorphic transition has been found at 181 K.

Keywords

nitrates of rare earth elements, urea, X-ray diffraction analysis, polymorphism

About the authors

I. A. Karavaev

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

E. V. Savinkina

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

S. S. Ponkrashina

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

M. S. Grigor’ev

Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: savinkina@mirea.ru
119071, Moscow, Russia

References

Borysiewicz M.A. // Crystals. 2019. T. 9. №. 10. C. 505. https://doi.org/10.3390/cryst9100505
Лыкошин Д.Д., Зайцев В.В., Костромина М.А., Есипов Р.С. // Тонкие химические технологии. 2021. Т. 16. № 1. С. 36.
Николаева Н.С., Иванов В.В., Шубин А.А. // Журн. Сибирского федерального университета. Химия. 2010. Т. 3. № 2. С. 153
Husairi F. S., Ali S. M., Azlinda A. et al. // J. Nanomat. 2013. V. 2013. P. 163527. https://doi.org/10.1155/2013/163527
Varma A., Mukasyan A.S., Rogachev A.S., Manukyan K.V. // Chem. Rev. 2016. V. 116. № 23. P. 14493. https://doi.org/10.1021/acs.chemrev.6b00279
Pathak T.K., Kumar A., Swart C.W. et al. // RSC Adv. 2016. V. 6. P. 97770. https://doi.org/10.1039/c6ra22341a
Moiseev N.V., Amosov A.P., Novikov V.A. et al. // AIP Conf. Proc. 2020. V. 2304. P. 020011. https://doi.org/10.1063/5.0034761
Smeets S., Lutz M. // Acta Crystallogr. Sect. C. 2011. V. 67. № 2. P. m50. https://doi.org/10.1107/S0108270111000023
Prior T.J., Kift R.L. // J. Chem. Crystallogr. 2009. V. 39. № 8. P. 558. https://doi.org/10.1007/s10870-009-9517-0
Koslowski N., Sanctis S., Hoffmann R.C. et al. // J. Mat. Chem. C. 2019. V. 7. № 4. P. 1048. https://doi.org/10.1039/C8TC04660C
Edwards R.A., Easteal A.J., Gladkikh O.P. et al. // Acta Crystallogr., Sect. B. 1998. V. 54. P. 663. https://doi.org/10.1107/S0108768198000536
Baltrusaitis J., Sviklas A.M. // ACS Sustainable Chem. Eng. 2015. V. 3. № 5. P. 950. https://doi.org/10.1021/acssuschemeng.5b00067
Hussein G.A.M. // J. Anal. Appl. Pyrolysis. 1996. V. 37. № 2. P. 111. https://doi.org/10.1016/0165-2370(96)00941-2
Zhan W., Guo Y., Gong X. et al. // Chin. J. Catal. 2014. V. 35. № 8. P. 1238. https://doi.org/10.1016/S1872-2067(14)60189-3
Solubilities Data Series. V. 13. Scandium, Yttrium, Lanthanum and Lanthanide Nitrates / Eds. Siekierski S., Salomon M., Mioduski T. London: Pergamon, 1983. 514 p.
Кусков В.И., Треушников Е.Н., Соболева Л.В. и др. // Докл. АН СССР. 1978. Т. 239. № 5. С. 1097.
Фурманова Н.Г., Сулайманкулова Д.Н., Худайбергенова Н.Б. и др. // Кристаллография. 1995. Т. 40. № 6. С. 999.
Koslowski N., Hoffmann R.C., Trouillet V. et al. // RSC Adv. 2019. V. 9. P. 31386. https://doi.org/10.1039/C9RA05348D
Savinkina E.V., Karavaev I.A., Grigoriev M.S. et al. // Inorg. Chim. Acta. 2022. V. 532. P. 120759. https://doi.org/10.1016/j.ica.2021.120759
Караваев И.А., Савинкина Е.В., Григорьев М.С. и др. // Журн. неорган. химии. 2022. Т. 67. № 8. С. 1080.
Savinkina E.V., Karavaev I.A., Grigoriev M.S. // Polyhedron. 2020. V. 192. P. 114875. https://doi.org/10.1016/j.poly.2020.114875
Садиков Г.Г., Сергиенко В.С., Порай-Кошиц М.А., Сулейманов Х. // Коорд. химия. 1987. Т. 13. № 5. С. 689.
Patrovsky V. // Collect. Czech. Chem. Commun. 1959. V. 24. P. 3305.
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. № 1. P. 3. https://doi.org/10.1107/S1600576714022985
Sheldrick G.M. // Acta Crystallogr., Sect. A. 2008. V. 64. № 1. P. 112. https://doi.org/10.1107/S0108767307043930
Sheldrick G.M. // Acta Crystallogr., Sect. C. 2015. V. 714. № 1. P. 3. https://doi.org/10.1107/S2053229614024218
Накамото К. // ИК-спектры и спектры КР неорганических и координационных соединений. М.: Мир, 1991. 536 с.
Рау Т.Ф., Куркутова Е.Н. // Докл. Акад. наук СССР. 1972. Т. 204. № 3. С. 600.
Sastri V.R., Perumareddi J.R., Rao V.R. et al. Modern Aspects of Rare Earths and Their Complexes. Elsevier, 2003. P. 412.