Spectral Studies of Coordination of 1-Methyl-2-(pyridin-4-yl)-3,4-fullero[60]pyrrolidine by Highly Substituted Cobalt(II) Porphyrin

N. G. Bichan; Бичан Н. Г.; V. A. Mozgova; Мозгова В. А.; E. N. Ovchenkova; Овченкова Е. Н.; M. S. Gruzdev; Груздев М. С.; T. N. Lomova; Ломова Т. Н.

doi:10.31857/S0044457X23600081

Spectral Studies of Coordination of 1-Methyl-2-(pyridin-4-yl)-3,4-fullero[60]pyrrolidine by Highly Substituted Cobalt(II) Porphyrin

Authors: Bichan N.G.¹, Mozgova V.A.¹, Ovchenkova E.N.¹, Gruzdev M.S.¹, Lomova T.N.¹
Affiliations:
1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 7 (2023)
Pages: 930-938
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://ruspoj.com/0044-457X/article/view/665226
DOI: https://doi.org/10.31857/S0044457X23600081
EDN: https://elibrary.ru/RIICFS
ID: 665226

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Abstract

A new dendrimeric cobalt(II) complex CoP has been obtained when reacting (5,15-bis[3,5-bis(tert-butyl)phenyl]-10,20-bis{4,6-bis[3,5-bis(3,6-di-tert-butylcarbazole-9-yl)phenoxy]pyrimidin-5-yl}porphine with Co(AcO)2·4H2O. The process of two-step two-way coordination of 1-methyl-2-(pyridin-4'-yl)-3,4-fullero[60]pyrrolidine (PyC60) with cobalt(II) porphyrin ends with the formation of a stable 1 : 2 complex, a triad of composition (PyC60)2CoP. The process has been completely kinetically described using UV-vis and fluorescent spectroscopy data. The stability constant (K) of the coordination complex is (9.9 ± 2.4) × 108 L2 mol–2 (log K = 9.0). The chemical structure of the triad has been determined by UV-vis, 1H NMR, and IR spectroscopy. The effect of PyC60 fluorescence quenching in the triad has been found and studied, and the static mechanism of the quenching process has been substantiated. The result can be used in optoelectronics to optimize the structures of donor–acceptor systems with the property of photoinduced electron transfer.

Keywords

cobalt(II) porphyrin, fullero[60]pyrrolidine, donor–acceptor triad, chemical structure, formation kinetics, photophysical properties

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