Polymorphism in the Mg3BPO7–Ni3BPO7 System

M. N. Smirnova; Смирнова М. Н.; M. A. Kop’eva; Копьева М. А.; G. D. Nipan; Нипан Г. Д.; G. E. Nikiforova; Никифорова Г. Е.; A. D. Yapryntsev; Япрынцев А. Д.; A. A. Arkhipenko; Архипенко А. А.; M. S. Doronina; Доронина М. С.

doi:10.31857/S0044457X2260236X

Polymorphism in the Mg3BPO7–Ni3BPO7 System

Authors: Smirnova M.N.¹, Kop’eva M.A.¹, Nipan G.D.¹, Nikiforova G.E.¹, Yapryntsev A.D.¹, Arkhipenko A.A.¹, Doronina M.S.²
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 6 (2023)
Pages: 746-751
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://ruspoj.com/0044-457X/article/view/665238
DOI: https://doi.org/10.31857/S0044457X2260236X
EDN: https://elibrary.ru/UFWYXL
ID: 665238

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Abstract

The Mg3 – nNinBPO7 (n = 0.0, 0.5, 1.0, 1.5, 2.0, 2.5, and 3.0) samples were prepared by solid-phase reactions at 980°C followed by inertial cooling, and then were characterized by X-ray powder diffraction, IR spectroscopy, diffusive reflectance and X-ray fluorescence spectrometry. It was for the first time that experiments yielded Ni3BPO7 crystals having the β-Zn3BPO7 non-centrosymmetrical hexagonal structure. The α-Mg3BPO7 and Ni3BPO7 coexistence range was determined. The diffuse reflectance spectra of an Mg1.5Ni1.5BPO7 sample featured a strong Ni2+ absorption band in the blue spectral range.

Keywords

borophosphate, phase state

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