Synthesis of New Iminium Derivatives of Sulphonio-сloso-Decaborate Anion (Bu4N)[2-B10H9SC(NH2)R] (R = –CH3, –CH2CH3, –CH(CH3)2, –Ph, –PhCH3)

A. V. Golubev; Голубев А. В.; A. S. Kubasov; Кубасов А. С.; A. A. Lukoshkova; Лукошкова А. А.; N. A. Sarkisov; Саркисов Н. А.; I. V. Novikov; Новиков И. В.; P. A. Starodubets; Стародубец П. А.; A. Yu. Bykov; Быков А. Ю.; A. P. Zhdanov; Жданов А. П.; K. Yu. Zhizhin; Жижин К. Ю.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X23601487

Synthesis of New Iminium Derivatives of Sulphonio-сloso-Decaborate Anion (Bu4N)[2-B10H9SC(NH2)R] (R = –CH3, –CH2CH3, –CH(CH3)2, –Ph, –PhCH3)

Authors: Golubev A.V.¹, Kubasov A.S.¹, Lukoshkova A.A.¹, Sarkisov N.A.¹^,2, Novikov I.V.¹^,2, Starodubets P.A.¹^,3, Bykov A.Y.¹, Zhdanov A.P.¹, Zhizhin K.Y.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. MIREA—Russian Technological University
3. Mendeleev University of Chemical Technology of Russia
Issue: Vol 68, No 12 (2023)
Pages: 1731-1739
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://ruspoj.com/0044-457X/article/view/666049
DOI: https://doi.org/10.31857/S0044457X23601487
EDN: https://elibrary.ru/XEXONU
ID: 666049

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Abstract

New iminium derivatives of the sulfonio-closo-decaborate anion have been obtained in the form of tetrabutylammonium salts (Bu4N)[2-B10H9SC(NH2)R] (R = –CH3, –CH2CH3, –CH(CH3)2, –Ph, –PhCH3), in which the iminium group acts as a protective group and allows further modification of the boron cluster anion without acting the sulfonium group. The compounds have been studied by elemental analysis, IR and 11B, 1H, 13C NMR spectroscopies. The structure of compounds (Bu4N)[2-B10H9SC(NH2)CH3] and (Bu4N)[2-B10H9SC(NH2)Ph] has been confirmed by X-ray diffraction analysis. The yield of final compounds is >80%.

Keywords

boron clusters, closo-decaborate anion, sulfonium derivatives, iminium salts

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