Synthesis, Chemical Structure, and Ground- and Excited-State Spectral Characteristics of (Porphyrinato)(chloro)indium(III) and Its Complexes with C60 and Pyridyl-Substituted Fullero[60]pyrrolidine

E. N. Ovchenkova; Овченкова Е. Н.; N. G. Bichan; Бичан Н. Г.; T. N. Lomova; Ломова Т. Н.

doi:10.31857/S0044457X23600652

Synthesis, Chemical Structure, and Ground- and Excited-State Spectral Characteristics of (Porphyrinato)(chloro)indium(III) and Its Complexes with C60 and Pyridyl-Substituted Fullero[60]pyrrolidine

Authors: Ovchenkova E.N.¹, Bichan N.G.¹, Lomova T.N.¹
Affiliations:
1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 11 (2023)
Pages: 1578-1587
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://ruspoj.com/0044-457X/article/view/666141
DOI: https://doi.org/10.31857/S0044457X23600652
EDN: https://elibrary.ru/DJDWRN
ID: 666141

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Abstract

New complexes of [5,10,15,20-tetra-(4-methoxyphenyl)porphinato](chloro)indium(III) ((Cl)InTPP(p-OCH3)4) with unsubstituted C60 and 1-methyl-2-(pyridin-4'-yl)-3,4- fullero[60]pyrrolidine (PyC60) were synthesized in toluene. The stability constants of 1 : 1 complexes (dyads) were determined using UV-vis and fluorescence spectroscopy. The dyads were characterized by IR and 1H NMR spectroscopy data. It was established that fluorescence of (Cl)InTPP(p-OCH3)4 is quenched upon gradual addition of fullerenes. The numerical values of the Stern–Volmer quenching constants (KSV) were determined. The most important charge transfer characteristics of dyads (the lifetime of charge-separated states and charge separation and recombination constants), needed for further consideration of dyads based on indium(III) porphyrins as photoinduced electron transfer systems, were determined using femtosecond laser spectroscopy.

Keywords

indium(III) porphyrin, C60 fullerene, fullero[60]pyrrolidine, donor-acceptor complex, formation reaction kinetics, spectral characteristics

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