Polymeric lanthanide 2-iodoterephthalates: synthesis and structure

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Abstract

Four new heteroligand metal-organic coordination polymers based on lanthanides and 2-iodoterephthalate anions (2-I-BDC) were synthesized — [Sm2(2-I-BDC)3(DMF)2(H2O)2]·6DMF (1), [Sm2(2-I-BDC)3(DMF)2.5(H2O)1.5]·0.5DMF (2), [Eu2(2-I-BDC)3(DMF)4]·2DMF (3) and [Yb2(2-I-BDC)3(DMF)(H2O)3]·4.25DMF (4), the structure of which was determined by X-ray diffraction.

About the authors

М. А. Bondarenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: bondarenko@niic.nsc
Russian Federation, Novosibirsk

А. S. Zaguzin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: bondarenko@niic.nsc
Russian Federation, Novosibirsk

P. А. Abramov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: bondarenko@niic.nsc
Russian Federation, Novosibirsk

V. P. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: bondarenko@niic.nsc
Russian Federation, Novosibirsk

D. А. Zherebtsov

South Ural State University

Email: bondarenko@niic.nsc
Russian Federation, Chelyabinsk

S. А. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; South Ural State University; Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: bondarenko@niic.nsc
Russian Federation, Novosibirsk; Chelyabinsk; Irkutsk

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