Application Of Vanadyl Alkoxoacetylacetonate In Formation Of v2O5 Electrochromic Films

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Abstract

Crystal structure, morphology and electrochromic properties of V2O5 film, prepared using vanadyl alkoxoacetylacetonate as precursor, were studied. We have shown that the obtained vanadium pentoxide contains significant amount of V4+ cations, which is indicated by low electron work function among other things. This results in material possessing anodic electrochromism – coloring upon oxidation – with rapid bleaching process (1 s upon necessary potential application). Anodic coloration is observed in the whole visible light spectrum, as well as in near IR region up to 1100 nm. Obtained data show high prospects for approach to formation of V2O5-based films using vanadyl acetylacetonate as precursor and application of such films as components of smart windows and displays, optical properties of which could be controlled by electrical current application.

About the authors

P. Y. Gorobtsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

N. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

A. S. Mokrushin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

E. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

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