Application Of Vanadyl Alkoxoacetylacetonate In Formation Of v2O5 Electrochromic Films

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Crystal structure, morphology and electrochromic properties of V2O5 film, prepared using vanadyl alkoxoacetylacetonate as precursor, were studied. We have shown that the obtained vanadium pentoxide contains significant amount of V4+ cations, which is indicated by low electron work function among other things. This results in material possessing anodic electrochromism – coloring upon oxidation – with rapid bleaching process (1 s upon necessary potential application). Anodic coloration is observed in the whole visible light spectrum, as well as in near IR region up to 1100 nm. Obtained data show high prospects for approach to formation of V2O5-based films using vanadyl acetylacetonate as precursor and application of such films as components of smart windows and displays, optical properties of which could be controlled by electrical current application.

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作者简介

P. Gorobtsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: phigoros@gmail.com
俄罗斯联邦, Moscow, 119991

N. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
俄罗斯联邦, Moscow, 119991

A. Mokrushin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
俄罗斯联邦, Moscow, 119991

E. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
俄罗斯联邦, Moscow, 119991

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
俄罗斯联邦, Moscow, 119991

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2. Fig. 1. Diffractogram of the formed V2O5 film. The asterisk indicates reflexes related to the sublayer of a transparent electrode based on indium tin oxide.

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3. Fig. 2. Results of Raman (a) and IR spectroscopy (b) of the formed V2O5 film. The asterisk on the Raman spectrum indicates modes related to vibrations involving the V4+ cation. IR spectrum 1 refers to a pure glass substrate with a transparent electrode sublayer, IR spectrum 2 refers to a substrate with a V2O5 film applied.

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4. Fig. 3. AFM results of the obtained V2O5 film: a, b, c – topographic images, d – surface potential distribution map.

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5. Fig. 4. Results of measuring the electrochromic properties of the V2O5 film: a – CVA recorded with a potential change rate of 100 mV/s; b – a change in the transmission coefficient of an electrochromic cell based on the V2O5 film at a wavelength of 450 nm and a potential sweep during CVA recording; c – a change in the transmission coefficient of the cell at a wavelength of 450 nm and exposure for 3 minutes at 2.5 and -3.5 V; g are the transmission spectra of the cell in the visible and near-INFRARED ranges before the start of measurements and after 3 minutes of exposure at different potential values.

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