DOPED LITHIUM TITANATES AND THEIR COMPOSITES WITH CARBON NANOTUBES AS ANODES FOR LITHIUM-ION BATTERIES

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Lithium titanates Li4+xTi5–xMxO12 (M = Sc, Ga, Al, Cr; x= 0, 0.05, 0.1, 0.15) and their composites with carbon nanotubes were synthesized by the sol-gel method and characterized using X-ray diffraction, scanning electron microscopy, impedance and 7Li MAS NMR spectroscopy; their electrochemical testing was carried out. Doping with trivalent cations leads to a decrease in the mobility of lithium ions in Li4+xTi5–xMxO12, which indicates the dominance of lithium transport through vacancies in these materials. The best electrochemical characteristics are demonstrated by the Li4+xTi5–xMxO12 composites with carbon nanotubes.

作者简介

I. Stenina

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: stenina@igic.ras.ru
Moscow, Russia

T. Kulova

Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Moscow, Russia

А. Yaroslavtsev

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

参考

  1. Dunn B., Kamath H., Tarascon J.-M. // Science. 2011. V. 334. P. 928. https://doi.org/10.1126/science.1212741
  2. Varzi A., Thanner K., Scipioni R. et al. // J. Power Sources. 2020. V. 480. P. 228803. https://doi.org/10.1016/j.jpowsour.2020.228803
  3. Chen Y., Kang Y., Zhao Y. et al. // J. Energy Chem. 2021. V. 59. P. 83. doi.org/10.1016/j.jechem.2020.10.017
  4. Sashmitha K., Rani M.U. // Polym. Bull. 2023. V. 80. P. 89. https://doi.org/10.1007/s00289-021-04008-x
  5. Li Y., Li Y., Zhang L. et al. // J. Energy Chem. 2023. V. 77. P. 123. https://doi.org/10.1016/j.jechem.2022.10.026
  6. Hossain Md.H., Chowdhury M.A., Hossain N. et al. // Chem. Eng. J. Adv. 2023. V. 16. P. 100569. https://doi.org/10.1016/j.ceja.2023.100569
  7. Siller V., Gonzalez-Rosillo J.C., Nunez Eroles M. et al. // Mater. Today Energy. 2022. V. 25. P.100979. https://doi.org/10.1016/j.mtener.2022.100979
  8. Liu R., Ma G., Li H. // Ferroelectrics. 2021. V. 580. P. 172. https://doi.org/10.1080/00150193. 2021.1905737
  9. Stenina I.A., Yaroslavtsev A.B. // Pure Appl. Chem. 2017. V. 89. P. 1185. https://doi.org/10.1515/pac-2016-1204
  10. Yan H., Zhang D., Qilu et al. // Ceramics Int. 2021. V. 47. P. 5870. https://doi.org/10.1016/j.ceramint.2020.10.241
  11. Pal S., Roy S., Jalagam P. et al. // ACS Appl. Energy Mater. 2021. V. 4. P. 969. https://doi.org/10.1021/acsaem.0c02929
  12. Han C., He Y.-B., Liu M. et al. // J. Mater. Chem. A. 2017. V. 5. P. 6368. https://doi.org/10.1039/C7TA00303J
  13. Xu X., Carr C., Chen X. et al. // Adv. Energy Mater. 2021. V. 11. P. 2003309. https://doi.org/10.1002/aenm.202003309
  14. Zhu C., Fuchs T.,Weber S.A.L. et al. // Nat.Commun. 2023. V. 14. P. 1300. https://doi.org/10.1038/s41467-023-36792-7
  15. Bai X., Li T., Bai Y.-J. // Dalton Trans. 2020. V. 49. P. 10003. https://doi.org/10.1039/D0DT01719A
  16. Stenina I.A., Kulova T.L., Skundin A.M. et al. // Mater. Res. Bull. 2016. V. 75. P. 178. https://doi.org/10.1016/j.materresbull.2015.11.050
  17. Yi T.-F., Wei T.-T., Li Y. et al. // Energy Storage Mater. 2020. V. 26 P. 165. https://doi.org/10.1016/j.ensm.2019.12.042
  18. Zhang E., Zhang H. // Ceram. Int. 2019. V. 45. P. 7419. https://doi.org/10.1016/j.ceramint.2019.01.030
  19. Stenina I.A., Shaydullin R.R., Desyatov A.V. et al. // Electrochim. Acta. 2020. V. 364. P. 137330. https://doi.org/10.1016/j.electacta.2020.137330
  20. Li J., Zhang T., Han C. et al. // J. Mater. Chem. A. 2019. V. 7. P. 455. https://doi.org/10.1039/C8TA10680K
  21. Meng Q., Hao Q., Chen F. et al. // Mater. Charact. 2023. V. 203. P. 113089. https://doi.org/10.1016/j.matchar.2023.113089
  22. Deng X., Li W., Zhu M. et al. // Solid State Ionics. 2021. V. 364. P. 115614. https://doi.org/10.1016/j.ssi.2021.115614
  23. Hu Y.,Wang L., Zhu C. et al. // Appl. Surf. Sci. 2024. V. 656. P. 159619. https://doi.org/10.1016/j.apsusc.2024.159619
  24. Yin Y., Luo X., Xu B. // J. Alloys Compd. 2022. V. 904. P. 164026. https://doi.org/10.1016/j.jallcom.2022.164026
  25. Wang H., Wang L., Lin J. et al. // Electrochim. Acta. 2021. V. 368. P. 137470. https://doi.org/10.1016/j.electacta.2020.137470
  26. Yaroslavtsev A.B., Stenina I.A. // Surf. Innov. 2021. V. 9. P. 92. https://doi.org/10.1680/jsuin.20.00044
  27. Ding S., Jiang Z., Gu J. et al. // Front. Chem. Sci. Eng. 2021. V. 15. P. 148. https://doi.org/10.1007/s11705-020-2022-x
  28. Li X., Huang X., Chen Y. et al. // Electrochim. Acta. 2021. V. 390. P. 138874. https://doi.org/10.1016/j.electacta.2021.138874
  29. Ma G., Deng L., Liu R. et al. // J. Solid State Electrochem. 2022. V. 26. P. 2893. https://doi.org/10.1007/s10008-022-05296-7
  30. Ke J., Zhang Y., Wen Z. et al. // J. Mater. Chem. A. 2023. V. 11. P. 4428. https://doi.org/10.1039/D2TA09502E
  31. Jang I.-S., Kang S.H., Kang Y.C. et al. // Appl. Surf. Sci. 2022. V. 605. P. 154710. https://doi.org/10.1016/j.apsusc.2022.154710
  32. Stenina I., Shaydullin R., Kulova T. et al. // Energies. 2020. V. 13. P. 3941. https://doi.org/10.3390/en13153941
  33. Iniguez F.B., Jeong H., Mohamed A.Y. et al. // J. Ind. Eng. Chem. 2022. V. 112. P. 125. https://doi.org/10.1016/j.jiec.2022.05.005
  34. Liu K., Wang J., Man J. et al. // Int. J. Energy Res. 2021. V. 45. P. 4345. https://doi.org/10.1002/er.6100
  35. Nezamzadeh Ezhyeh Z., Khodaei M., Torabi F. // Ceram. Int. 2023. V. 49. P. 7105. https://doi.org/10.1016/j.ceramint.2022.04.340
  36. Hou L., Qin X., Gao X. et al. // J. Alloys Compd. 2019. V. 774. P. 38. https://doi.org/10.1016/j.jallcom.2018.09.364
  37. Ncube N.M., Mhlongo W.T., McCrindle R.I. et al. // Mater. Today: Proceed. 2018. V. 5. P. 10592. https://doi.org/10.1016/j.matpr.2017.12.392
  38. Meng Q., Chen F., Hao Q. et al. // J. Alloys Compd. 2021. V. 885. P. 160842. https://doi.org/10.1016/j.jallcom.2021.160842
  39. Kulova T.L., Kreshchenova Y.M., Kuz’mina A.A. et al. // Mendeleev Commun. 2016. V. 26. P. 238. https://doi.org/10.1016/j.mencom.2016.05.005
  40. Zou S., Wang G., Zhang Y. et al. // J. Alloys Compd. 2020. V. 816. P. 152609. https://doi.org/10.1016/j.jallcom.2019.152609
  41. Stenina I.A., Sobolev A.N., Yaroslavtsev S.A. et al. // Electrochim. Acta. 2016. V. 219. P. 524. https://doi.org/10.1016/j.electacta.2016.10.034
  42. Стенина И.А., Соболев А. Н., Кулова Т. Л. и др. // Журн. неорган. химии. 2022. Т. 67.№6. С. 829.
  43. Shannon R.D., Prewitt C.T. // Acta Crystallogr., Sect. B. 1969. V. 25. P. 925. https://doi.org/10.1107/S0567740869003220

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