Features of the changes in composition and structure of rare-earth halide complexes with acethylurea

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Resumo

Structures of rare-earth halide complexes with acetylurea (AcUr), [Sm(AcUr)2(H₂O)5]Cl3, [Eu(AcUr)2(H₂O)5]Br3 · · H₂O, [Ln(AcUr)2(H₂O)4]Br3 · H₂O (Ln = Tm, Yb), and [Lu(AcUr)(H₂O)6]Br3 were determined. Analysis of compositions and structures of these compounds along with the earlier reported analogues allowed us to consider the features of their changes depending on the atomic number of the element.It was found that the size of the central atom is the decisive factor.

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Sobre autores

P. Akulinina

Lomonosov Institute of Fine Chemical Technologies, RTU MIREA

Email: savinkina@mirea.ru
Rússia, 86 Vernadsky, Moscow, 119571

E. Savinkina

Lomonosov Institute of Fine Chemical Technologies, RTU MIREA

Autor responsável pela correspondência
Email: savinkina@mirea.ru
Rússia, 86 Vernadsky, Moscow, 119571

M. Grigoriev

Frumkin Institute of Physical Chemistry and Electrochemistry, RAS

Email: savinkina@mirea.ru
Rússia, 31, Bldg 4 Leninsky pr., Moscow, 119071

Bibliografia

  1. Paul R.Ch., Sood S., Chadha S.L. // J. Inorg. Nucl. Chem. 1971. V. 33. P. 2703.
  2. Усубалиева У., Ногоев К., Сулайманкулов К., Коваленко Л. // Журн. неорган. химии. 1976. Т. 21. № 4. С. 1100.
  3. Харитонов Ю.Я., Гущина Т.Н. // Журн. неорган. химии. 1987. Т. 32. № 2. С. 410.
  4. Аликберова Л.Ю., Альбов Д.В., Бушмелева А.С. и др. // Коорд. химия. 2014. Т. 40. № 12. С. 748. https://doi.org/10.1134/S1070328414120021
  5. Bushmeleva A.S., Alikberova L.Y., Albov D.V. Advancing Coordination, Bioinorganic and Applied Inorganic Chemistry. The 50th Anniversary of ICCBIC / Eds. Melník M., Segľa P., Tatarko M. Bratislava: Slovak Chemical Society, 2015. P. 27–40.
  6. Isbjakowa A.S., Grigoriev M.S., Golubev D.V., Savinkina E.V. // J. Mol. Struct. 2020. V. 1201. P. 127141. https://doi.org/10.1016/j.molstruc.2019.127141
  7. Savinkina E.V., Akulinin P.V., Golubev D.V., Grigoriev M.S. // Polyhedron. 2021. V. 204. P. 115258. https://doi.org/10.1016/j.poly.2021.115258
  8. Акулинин П.В., Савинкина Е.В., Григорьев М.С., Белоусов Ю.А. // Журн. неорган. химии. 2024. Т. 69. № 5. С. 727. https://doi.org/10.1134/S0036023624600072
  9. APEX2 // Bruker AXS Inc. 2007. Madison, Wisconsin, USA.
  10. Sheldrick G.M. SADABS // Bruker AXS Inc. 2004. Madison, Wisconsin, USA.
  11. Sheldrick G.M. SHELXS-97 and SHELXL-97, Program for Crystal Structure Solution and Refinement.Gottingen: University of Gottingen,1997.
  12. Sheldrick G.M. // Acta Crystallogr., Sect. C. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
  13. Лайков Д.Н., Устынюк Ю.А. // Изв. РАН. Сер. хим. 2005. Т. 54. № 3. С. 804. https://doi.org/10.1007/s11172-005-0329-x
  14. Perdew J.P., Burke K., Ernzerhof M. // Phys. Rev. Lett. 1996. V. 77. P. 3865. https://doi.org/10.1103/PhysRevLett.77.3865
  15. Laikov D.N. // Chem. Phys. Lett. 2005. V. 416. № 1–3. P. 116. https://doi.org/10.1016/j.cplett.2005.09.046
  16. Порай-Кошиц М.А., Асланов Л.А. // Журн. структур. химии. 1972. Т. 13. № 2. С. 266.
  17. Uno T., Machida K., Hanai K., Saito Y. // Bull. Chem. Soc. Jpn. 1969. V. 42. P. 619. https://doi.org/10.1246/bcsj.42.619
  18. Аликберова Л.Ю., Антоненко Т.А., Альбов Д.В. // Тонк. хим. технол. 2015. Т. 10. № 1. С. 66.
  19. Haddad S.F. // Acta Crystallogr., Sect. C. 1988. V. 44. № 5. P. 815. https://doi.org/10.1107/S010827018800054X.
  20. Haddad S.F. // Acta Crystallogr., Sect. C. 1987. V. 43. № 10. P. 1882. https://doi.org/10.1107/S0108270187089753.
  21. Корнилов А.Д., Григорьев М.С., Савинкина Е.В. // Тонк. хим. технол. 2022. Т. 17. № 2. С. 172. https://doi.org/10.32362/2410-6593-2022-17-2-172-181
  22. Антоненко Т.А., Аликберова Л.Ю., Альбов Д.В. и др. // Коорд. химия. 2013. Т. 39. № 3. С. 187. https://doi.org/10.1134/S1070328413020024
  23. Аликберова Л.Ю., Антоненко Т.А., Альбов Д.В. и др. // Тонк. хим. технол. 2013. Т. 8. № 4. С. 57.
  24. Cotton S.A. // ComptesRendus. Chimie. 2005. V. 8. № 2. P. 129. https://doi.org/10.1016/j.crci.2004.07.002
  25. Kim P., Anderko A., Navrotsky A., Riman R.E. // Minerals. 2018. V. 8. № 3. P. 106. https://doi.org/10.3390/min8030106
  26. Gumin´ski C., Voigt H., Zeng D. // Monatsh. Chem. 2011. V. 142. P. 211. https://doi.org/10.1007/s00706-011-0457-y
  27. Голикова М.В., Япрынцев А.Д., Цзя Ч. и др. // Журн. неорган. химии. 2023. Т. 68. № 10. С. 1422. https://doi.org/10.1134/S0036023623601800
  28. Bardonov D.A., Lyssenko K.A., Degtyareva S.S. et al. // Russ. J. Coord. Chem. 2024. V. 50. P. 334. https://doi.org/10.1134/S1070328423601565
  29. Savinkina E.V., Karavaev I.A., Grigoriev M.S. // Inorg. Chim. Acta. 2022. V. 532. P. 120759. https://doi.org/10.1016/j.ica.2021.120759
  30. Kiskin M.A., Konnik O.V., Shul’gin V.F. et al. // Russ. J. Coord. Chem. 2024. V. 50. P. 476. https://doi.org/10.1134/S107032842460030X
  31. Сулейманов X., Порай-Кошиц M.А., Анцышкина A.C., Сулайманкулов К. // Журн. неорган. химии. 1971. Т. 16. № 12. С. 3394.
  32. Drakopoulou L., Papatriantafyllopoulou C., Terzis A. et al. // Bioinorg. Chem. Appl. 2007. V. 2007. № 1. P. 051567.
  33. https://doi.org/10.1155/2007/51567
  34. Заполоцкий Е.Н., Бабайлов С.П. // Журн. неорган. химии. 2022. Т. 67. № 11. С. 1646. https://doi.org/10.1134/S0036023622601064
  35. Verma G., Hostert J., Summerville A.A. et al. // ACS Appl. Mater. Interfaces. 2024. V. 16. № 13. P. 16912. https://doi.org/10.1021/acsami.3c17565
  36. Dong Z., Mattocks J.A., Deblonde G.J. et al. // ACS Cent. Sci. 2021. V. 7. № 11. P. 1798. https://doi.org/10.1021/acscentsci.1c00724
  37. Ye Q., Wang D., Wei N. // Trends Biotechnol. 2024. V. 42. № 5. P. 575. https://doi.org/10.1016/j.tibtech.2023.10.011

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2. Fig. 1. Structure of the compound [Eu(AcUr)2(H2O)5]Br3 · H2O (I) at 100K according to X-ray diffraction data. Temperature shift ellipsoids are shown with a probability of 50%, hydrogen atoms are not shown.

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3. Fig. 2. Structure of the compound [Tm(AcUr)2(H2O)4]Br3 · H2O (II) at 100 K according to X-ray diffraction data. Temperature shift ellipsoids are shown with a probability of 50%, hydrogen atoms are not shown.

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4. Fig. 3. Structure of the compound [Lu(AcUr)(H2O)6]Br3 (IV) at 100 K according to X-ray diffraction data. Temperature shift ellipsoids are shown with a probability of 50%, hydrogen atoms are not shown.

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5. Fig. 4. General view of the starting geometry for connection II.

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6. Supplementary
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7. Supplementary
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