Effective synthesis of 3,5-bis(sulfanylmethyl)-1,4-oxaselenanes

А. G. Khabibulina; Хабибулина А. Г.

doi:10.31857/S0044460X24100014

Effective synthesis of 3,5-bis(sulfanylmethyl)-1,4-oxaselenanes

Authors: Khabibulina А.G.¹
Affiliations:
1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Issue: Vol 94, No 10 (2024)
Pages: 1014-1020
Section: Articles
URL: https://ruspoj.com/0044-460X/article/view/676649
DOI: https://doi.org/10.31857/S0044460X24100014
EDN: https://elibrary.ru/RFQVIA
ID: 676649

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Abstract

Methods for the synthesis of 3,5-bis(organylsulfanylmethyl)-1,4-oxaselenanes based on diallyl ether, selenium dibromide and thiocarbamide using a bis-isothiouronium derivative as a source of the corresponding dithiolate anions, which were involved into a nucleophilic addition reaction to acrylates and substitution with various alkyl halides. As a result, methods for obtaining dialkyl derivatives in 90–98% yields and the products of addition of dithiolate anions to acrylates in 74–91% yields were developed.

Keywords

diallyl ether, 3,5-bis(alkylsulfanylmethyl)-1,4-oxaselenanes, dithiolate anion, oxaselenanes, acrylates

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About the authors

А. G. Khabibulina

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: almah@irioch.irk.ru
ORCID iD: 0000-0003-3523-9794
Russian Federation, 664033, Irkutsk

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