Electrochemical Determination of Streptomycin on an Electrode Modified with a Composite of Graphene Oxide and Gold–Nickel Binary System

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

A procedure was suggested for voltammetric determination of streptomycin from the catalytic current on a glassy carbon electrode with a composite based on reduced graphene oxide and gold–nickel binary system. The working conditions of the electrode modification (volume of the graphene oxide and chitosan suspension, duration of the electrolytic reduction of immobilized graphene oxide and electrodeposition of the gold–nickel binary system) and the conditions for recording the catalytic current in the flow injection system were determined. The procedure for streptomycin determination in a flow, compared to the determination under stationary conditions, is more sensitive, reproducible, and rapid. The streptomycin detection limit was 0.45 nmol, and the productive capacity of the analysis was 60 samples per hour. The streptomycin determination procedure passed trials in analysis of cow milk.

About the authors

L. G. Shaydarova

Butlerov Chemical Institute, Kazan Federal University, Kazan, 420008, Tatarstan, Russia

Email: acjournal.nauka.nw@yandex.ru

A. A. Pozdnyak

Butlerov Chemical Institute, Kazan Federal University, Kazan, 420008, Tatarstan, Russia

Email: acjournal.nauka.nw@yandex.ru

A. V. Gedmina

Butlerov Chemical Institute, Kazan Federal University, Kazan, 420008, Tatarstan, Russia

Email: acjournal.nauka.nw@yandex.ru

I. A. Chelnokova

Butlerov Chemical Institute, Kazan Federal University, Kazan, 420008, Tatarstan, Russia

Email: acjournal.nauka.nw@yandex.ru

D. A. Murdasova

Butlerov Chemical Institute, Kazan Federal University, Kazan, 420008, Tatarstan, Russia

Email: acjournal.nauka.nw@yandex.ru

G. K. Budnikov

Butlerov Chemical Institute, Kazan Federal University, Kazan, 420008, Tatarstan, Russia

Author for correspondence.
Email: acjournal.nauka.nw@yandex.ru

References

  1. Навашин С. М., Фомина И. П., Сазыкин Ю. О. Антибиотики группы аминогликозидов. М.: Медицина, 1977. С. 103.
  2. Кулапина Е. Г., Баринова О. В., Кулапина О. И., Утц И. А., Снесарев С. В. Современные методы определения антибиотиков в биологических и лекарственных средах (обзор) // Антибиотики и химиотерапия. 2009. Т. 54. № 9-10. С. 53-60. EDN: RWZYIN
  3. Leech D., Wang J., Smyth M. R. Electrocatalytic detection of streptomycin and related antibiotics at ruthenium dioxide modified graphite-epoxy composite electrodes // Analyst. 1990. V. 115. N 11. P. 1447-1450. https://doi.org/10.1039/an9901501447
  4. Akbarzadeh S., Khajesharifi H., Thompson M. Simultaneous determination of streptomycin and oxytetracycline using a oracet-blue/silver-nanoparticle/ graphene-oxide/modified screen-printed electrode // Biosensors. 2020. V. 10. N 3. ID 23. https://doi.org/10.3390/bios10030023
  5. Wen Y., Liao X., Deng C., Liu G., Yan Q., Li L., Wang X. Imprinted voltammetric streptomycin sensor based on a glassy carbon electrode modified with electropolymerized poly (pyrrole-3-carboxy acid) and electrochemically reduced graphene oxide // Microchim. Acta. 2017. V. 184. N 3. P. 935-941. https://doi.org/10.1007/s00604-017-2089-3
  6. Darabdhara G., Das M. R., Singh S. P., Rengan A. K., Szunerits S., Boukherroub R. Ag and Au nanoparticles/ reduced graphene oxide composite materials: Synthesis and application in diagnostics and therapeutics // Adv. Colloid Interface Sci. 2019. V. 271. P. 101991. https://doi.org/10.1016/j.cis.2019.101991
  7. Zou C. E., Zhong J., Li S., Wang H., Wang J., Yan B., Du Y. Fabrication of reduced graphene oxide-bimetallic PdAu nanocomposites for the electrochemical determination of ascorbic acid, dopamine, uric acid and rutin. //j. Electroanal. Chem. 2017. V. 805. P. 110-119. https://doi.org/10.1016/j.jelechem.2017.10.020
  8. Tadayon F., Vahed S., Bagheri H. Au-Pd/reduced graphene oxide composite as a new sensing layer for electrochemical determination of ascorbic acid, acetaminophen and tyrosine // Mater. Sci. Eng. 2016. V. 68. P. 805-813. https://doi.org/10.1016/j.msec.2016.07.039
  9. Fedorchuk V. A., Puchkovskaya E. S., Anisimova L. S., Slepchenko G. B. Use of voltammetry for determining antibiotics streptomycin and azithromycin //j. Anal. Chem. 2005. V. 60. N 6. P. 518-522. https://doi.org/10.1007/s10809-005-0132-8
  10. Sato K., Jin J. Y., Takeuchi T., Miwa T., Takekoshi Y., Kanno S., Kawase S. Nickel-titanium alloy electrodes for stable amperometric detection of underivatized amino acids in anion-exchange chromatography // Talanta. 2001. V. 53. N 5. P. 1037-1044. https://doi.org/10.1016/S0039-9140(00)00596-8
  11. Burke L. D. The scope for new application for gold arising from the electrocatalytic behaviour of its metastable surface states //Gold Bull. 2004. V. 37. N 1-2. P. 125-135. https://doi.org/10.1007/BF0321552

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Statistics

Views

Abstract: 1644

Dimensions

Article Metrics

Metrics Loading ...

PlumX


Copyright (c) 2023 Russian Academy of Sciences