Furancarboxylate Coordination Polymers of Gd3+ and Eu3+: Synthesis,
Structural Variations, and Biological Properties

M. A. Uvarova; Уварова М. А.; I. A. Lutsenko; Луценко И. А.; M. A. Shmelev; Шмелев М. А.; O. B. Bekker; Беккер О. Б.; M. A. Kiskin; Кискин М. А.; I. L. Eremenko; Еременко И. Л.

doi:10.31857/S0132344X23600029

Furancarboxylate Coordination Polymers of Gd3+ and Eu3+: Synthesis, Structural Variations, and Biological Properties

Authors: Uvarova M.A.¹, Lutsenko I.A.¹, Shmelev M.A.¹, Bekker O.B.², Kiskin M.A.¹, Eremenko I.L.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
2. Vavilov Institute of General Genetics, Russian Academy of Sciences, Moscow, Russia
Issue: Vol 49, No 9 (2023)
Pages: 543-552
Section: Articles
URL: https://ruspoj.com/0132-344X/article/view/667481
DOI: https://doi.org/10.31857/S0132344X23600029
EDN: https://elibrary.ru/WATJKU
ID: 667481

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Abstract

A series of polymer complexes of Gd(III) and Eu(III) with 3-furancarboxylic (HFur) and 5-nitro-
2-furancarboxylic (HNfur) acids differed in the composition and coligands presented by solvent molecules
(CH3OH/C2H5OH/H2O) is synthesized: [Gd(Fur)3(CH3OH)(C2H5OH)]n (I), [Gd(Nfur)3(CH3OH)2]n·
CH3CN (II), [Eu(Fur)3(C2H5OH)]n (III), and [Eu(Nfur)3(H2O)2]n·3CH3CN (IV). According to the X-ray
diffraction (XRD) data, all complexes are 1D coordination polymers in which the lanthanide cation has the
coordination number 8 (LnO8) to form the environment as a doubly augmented triangular prism (I, II) or a
square antiprism (III, IV). The supramolecular levels of the polymers are stabilized due to intra- and intermolecular
hydrogen bonds between the coordinated solvent molecules and O atoms of the chelate-bound
anions of the acid and via two types of noncovalent C–H…O and N–O…π interactions that significantly contribute
to an additional stabilization of the crystal packings. The biological properties of complexes I, II, and
IV are studied with respect to the model nonpathogenic strain Mycolicibacterium smegmatis.

Keywords

rare-earth element complexes, gadolinium(III), europium(III), 3-furancarboxylic acid, 5-nitro-2-furancarboxylic acid, crystal structure, coordination polymers

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