Copper(II) o-Iminophenolate Complexes Based on Catecholaldimines

S. V. Baryshnikova; Барышникова С. В.; M. V. Arsen’ev; Арсеньев М. В.; R. V. Rumyantsev; Румянцев Р. В.; I. A. Yakushev; Якушев И. А.; A. I. Poddel’skii; Поддельский А. И.

doi:10.31857/S0132344X22600643

Copper(II) o-Iminophenolate Complexes Based on Catecholaldimines

Authors: Baryshnikova S.V.¹, Arsen’ev M.V.¹, Rumyantsev R.V.¹, Yakushev I.A.², Poddel’skii A.I.¹
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
Issue: Vol 49, No 7 (2023)
Pages: 422-430
Section: Articles
URL: https://ruspoj.com/0132-344X/article/view/667497
DOI: https://doi.org/10.31857/S0132344X22600643
EDN: https://elibrary.ru/TVKHLA
ID: 667497

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Abstract

The exchange reactions of 4,6-di-tert-butylpyrocatechols containing in position 3 different N‑aryliminomethyl groups (aryl is p-halophenyl; halogen is fluorine (I), chlorine (II), bromine (III), and iodine (IV); p-tolyl (V)) with copper(II) acetate in a molar ratio of 2 : 1 afford planar square copper(II) o‑iminophenolate complexes of the general formula [(R-CatH)2Cu], where R is the aryl substituent in the Ar–N=CH group. The molecular structures of complexes I, III, and V in the crystalline state are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2227448 (I), 2226727 (III), and 2227449 (V)). The electrochemical properties of compounds I–V are studied by cyclic voltammetry.

Keywords

pyrocatechol, Schiff base, copper(II), cyclic voltammetry, XRD

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