Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties

L. G. Lavrenova; Лавренова Л. Г.; E. Yu. Grigor’ev; Григорьев Е. Ю.; V. Yu. Komarov; Комаров В. Ю.; L. A. Glinskaya; Глинская Л. А.; A. N. Lavrov; Лавров А. Н.; Yu. V. Grigor’ev; Григорьев Ю. В.

doi:10.31857/S0132344X2260028X

Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties

Authors: Lavrenova L.G.¹, Grigor’ev E.Y.², Komarov V.Y.¹, Glinskaya L.A.¹, Lavrov A.N.¹^,3, Grigor’ev Y.V.²
Affiliations:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2. Institute of Physicochemical Problems, Belarussian State University, Minsk, Belarus
3. Novosibirsk National Research State University, Novosibirsk, Russia
Issue: Vol 49, No 2 (2023)
Pages: 111-121
Section: Articles
URL: https://ruspoj.com/0132-344X/article/view/667532
DOI: https://doi.org/10.31857/S0132344X2260028X
EDN: https://elibrary.ru/BNQVZK
ID: 667532

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Abstract

A procedure for the synthesis of the new ditopic ligand combining in the structure 1- and 5-substituted tetrazolyl cycles, 5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole (HL), is developed. The coordination compounds of Co(II) and Cu(II) halides [Co(HL)2Cl2], [Cu(HL)2Cl2], [Cu(HL)2Br2], and [CuL2(H2O)]n based on ligand HL are synthesized. The complexes are studied by elemental analysis, diffuse reflectance spectroscopy, IR spectroscopy, X-ray diffraction (XRD), and static magnetic susceptibility. The crystal structure of the molecular coordination polymer [CuL2(H2O)]n is determined by XRD (CIF file CCDC no. 2127210). The temperature and field dependences of the magnetization show that the magnetic properties of the synthesized Cu(II) complexes are due to exchange interactions in one-dimensional chains of the copper ions (S = 1/2). For complex [Cu(HL)2Br2], the parameters are shifted toward the enhancement of the antiferromagnetic interaction compared to the analog containing the chloride ion.

Keywords

synthesis, 5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole, cobalt(II) and copper(II) complexes, XRD, diffuse reflectance spectroscopy, IR spectroscopy, magnetic activity

References

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