Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid

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Compounds of three types, [LnL3(C2H5OH)] (Ln = Nd (I), Sm (II), Eu (III)), [LnL3(H2O)] (Ln = = Gd (IV), Tb (V)), and [DyL2(NO3)(C2H5OH)2] (VI), were obtained by reactions of lanthanide nitrate with NaL (L– = 2,4-dichlorophenoxyacetate anion) in ethanol. The composition and structure of complexes I–VI were investigated by elemental and thermogravimetric analysis, IR spectroscopy, and X-ray diffraction (nos. 2311578 (I), 2311579 (II), 2311580 (III) 2311581 (IV), 2311582 (VI)). All compounds have a one-dimensional polymer structure in which metal atoms are connected by bridging carboxylate groups. The π–π interactions and intermolecular contacts between the chains give rise to a three-dimensional supramolecular structure.

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作者简介

M. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shuvic@gmail.com
俄罗斯联邦, Moscow

O. Konnik

Vernadsky Crimea Federal University

Email: shuvic@gmail.com
俄罗斯联邦, Simferopol

V. Shulgin

Vernadsky Crimea Federal University

编辑信件的主要联系方式.
Email: shuvic@gmail.com
俄罗斯联邦, Simferopol

A. Gusev

Vernadsky Crimea Federal University

Email: shuvic@gmail.com
俄罗斯联邦, Simferopol

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2. Fig. 1. Centrosymmetric dimeric fragment of the polymer chain in III (different ways of coordination of carboxylate anion are shown)

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3. Fig. 2. Fragment of the polymer chain in IV (different ways of coordination of carboxylate anion are shown)

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4. Fig. 3. Fragment of the polymer chain in VI

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5. Fig. 4. Fragment of crystal packing II (carbon atoms of benzene rings bound by π...π- interactions are numbered)

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6. Fig. 5. Fragment of crystal packing IV (carbon atoms of benzene rings bound by π...π- interactions are numbered)

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7. Fig. 6. Fragment of crystal packing VI (carbon atoms of benzene rings bound by π...π- interactions are numbered)

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