Reactions of palladium(II) chloride with monoiminoacenaphthenones

A. N. Lukoyanov; Лукоянов А. Н.; N. F. Romashev; Ромашев Н. Ф.; V. I. Komlyagina; Комлягина В. И.; V. V. Kokovkin; Коковкин В. В.; A. V. Cherkasov; Черкасов А. В.; A. L. Gushchin; Гущин А. Л.

doi:10.31857/S0132344X23600595

Reactions of palladium(II) chloride with monoiminoacenaphthenones

Authors: Lukoyanov A.N.¹, Romashev N.F.², Komlyagina V.I.²^,3, Kokovkin V.V.², Cherkasov A.V.¹, Gushchin A.L.²
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3. Novosibirsk State University, Novosibirsk, Russia
Issue: Vol 49, No 12 (2023)
Pages: 760-766
Section: Articles
URL: https://ruspoj.com/0132-344X/article/view/667635
DOI: https://doi.org/10.31857/S0132344X23600595
EDN: https://elibrary.ru/LGNPMA
ID: 667635

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Abstract

When PdCl2 reacts with [2,6-diisopropylphenyl]iminoacenaphthenone (dpp-mian) in dichloromethane, the compound 2[Pd(dpp-mian)Cl2]*[Pd(dpp-mian)2Cl2] (1) is formed. It contains two structural units: [Pd(dpp-mian)Cl2], in which dpp-mian is coordinated to Pd(II) in a bidentate-chelate manner by nitrogen and oxygen atoms, and [Pd(dpp-mian)2Cl2], in which two dpp-mian molecules are bonded to palladium only through a nitrogen atom. On the other hand, when PdCl2 interacts with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane, a rearrangement of the ligand structure occurs, followed by the formation of the previously described in the literature complex of Pd(II) with 1,2-bis-[4-methoxyphenyl ]iminoacenaphthene (4-MeOPh-bian) of the composition [Pd(4-MeOPh-bian)Cl2] (2). Compound 1 was obtained for the first time and characterized by X-ray diffraction, as well as by X-ray diffraction, elemental analysis, IR spectroscopy and cyclic voltammetry.

Keywords

palladium, iminoacenaphthenones, X-ray diffraction analysis, complexes, synthesis, cyclic voltammetry

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