Ditopic Centrosymmetric Mercaptobenzothiazole Dilithium Salts: From the Molecular Complex to Luminescent 1D Metal-Organic Frameworks

A. F. Rogozhin; Рогожин А. Ф.; V. A. Ilyichev; Ильичев В. А.; L. I. Silantyeva; Силантьева Л. И.; E. A. Kozlova; Козлова Е. А.; G. K. Fukin; Фукин Г. К.; M. N. Bochkarev; Бочкарев М. Н.

doi:10.31857/S0132344X24100048

Ditopic Centrosymmetric Mercaptobenzothiazole Dilithium Salts: From the Molecular Complex to Luminescent 1D Metal-Organic Frameworks

Authors: Rogozhin A.F.¹, Ilyichev V.A.¹, Silantyeva L.I.¹, Kozlova E.A.¹, Fukin G.K.¹, Bochkarev M.N.¹
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Issue: Vol 50, No 10 (2024)
Pages: 669-678
Section: Articles
URL: https://ruspoj.com/0132-344X/article/view/667655
DOI: https://doi.org/10.31857/S0132344X24100048
EDN: https://elibrary.ru/LPVOOX
ID: 667655

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Abstract

The reaction of lithium amide LiN(Si(Me)₃)₂ and ditopic heterocyclic ligand benzo[1,2-d:4,5-d′]bis(thiazole)-2,6(3H,7H)-dithione (H₂L) in dimethoxyethane (DME) affords the binuclear molecular complex Li₂L(DME)₄(I). New compounds [[Li₂L(ДМСО)₄• (ДМСО)₂]_n(II) and [Li₂L(ДМСО)₄• (ТГФ)₂]_n(III) are prepared by the recrystallization of compound I using a DMSO–diethyl ether or DMSO/THF mixture of solvents, respectively. According to the XRD data, these compounds are one-dimensional metalorganic frameworks (MOFs) differed by the arrangement of the bis(thiazole) fragments relative to each other and the Li₂O₂ fragment in the polymer chain, which affects the luminescence properties. The molecular structures of compounds I–III are determined by XRD (CIF files CCDC nos. 2334192 (I), 2334193 (II), and 2334194 (III)).

Keywords

2-mercaptobenzothiazole, phosphorescence, fluorescence, heterocyclic ligands, lithium, metalorganic framework

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