Superhydrophobic Coating Based on Decorated Carbon Nanoparticles

S. N. Kapustin; Капустин С. Н.; M. K. Eseev; Есеев М. К.; Yu. V. Tsykareva; Цыкарева Ю. В.; V. I. Voshchikov; Вощиков В. И.; D. S. Lugvishchuk; Лугвищук Д. С.

doi:10.31857/S0132665123600279

Superhydrophobic Coating Based on Decorated Carbon Nanoparticles

Authors: Kapustin S.N.¹, Eseev M.K.¹, Tsykareva Y.V.¹, Voshchikov V.I.², Lugvishchuk D.S.³
Affiliations:
1. Department of Fundamental and Applied Physics, Lomonosov Northern (Arctic) Federal University, 163002, Arkhangelsk, Russia
2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia
3. Technological Institute for Superhard and New Carbon Materials, 108840, Troitsk, Moscow, Russia
Issue: Vol 49, No 5 (2023)
Pages: 554-566
Section: Articles
URL: https://ruspoj.com/0132-6651/article/view/663356
DOI: https://doi.org/10.31857/S0132665123600279
EDN: https://elibrary.ru/WRZVMV
ID: 663356

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

A method is proposed for increasing the resistance of a superhydrophobic coating based on a CNT xerogel to frost deposition through the use of decorating nanoparticles. The effects of the addition of fullerenes, carbon nanoonions (CNOs), detonation nanodiamonds, silicon dioxide, and paraffin to the xerogel are tested. An increase in the resistance of the coating to the deposition of condensate in the form of frost is revealed. The addition of fullerene C60 leads to the best results. Increasing the resistance to icing allows us to spend less power on heating the surface during short cold snaps, bypassing the anti-icing properties of the protective superhydrophobic layer. However, the application of this approach shows a deterioration in the resistance of the coating to the penetration of the spray. This is given a qualitative explanation and measures to combat it are proposed. No effect of the additives on the mechanical properties of the coating or its resistance to damage is detected. In additon, decorating additives affect the formation of the coating relief. With this, it is possible to influence the stochastic processes of the formation of roughness during the drying of the xerogel.

Keywords

superhydrophobicity, carbon nanotubes, fullerenes, detonation nanodiamonds, decoration

References

Boinovich L.B., Emelyanenko A.M. Anti-icing Potential of Superhydrophobic Coatings // Mendeleev Commun. 2013. V. 23. Iss. 1. P. 3–10.
Barthlott W., Neinhuis C. Purity of the sacred lotus, or escape from contamination in biological surfaces // Planta. 1997. V. 202. P. 1–8.
Wong T.S., Kang S.H., Tang S.K.Y., Smythe E.J., Hatton B.D., Grinthal A., Aizenber J. Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity // Nature 2011. V. 477. P. 443–447.
Соловьянчик Л.В., Кондрашов С.В., Нагорная В.С., Мельников А.А. Особенности получения антиобледенительных покрытий (обзор) // Труды ВИАМ. 2018. № 6. С. 66.
Соловьянчик Л.В., Кондрашов С.В. Перспективность использования углеродных нанотрубок для придания поверхности полимерных материалов функциональных свойств (обзор) // Труды ВИАМ. 2021. № 9 С. 103.
Бойнович Л.Б., Емельяненко А.М. Гидрофобные материалы и покрытия: принципы создания, свойства, применение // Успехи химии. 2008. Т. 77. № 7. С. 619–638.
Соловьянчик Л.В., Кондратов C.B., Нагорная B.C., Волков И.А., Дьячкова Т.П., Борисов К.М. Электропроводящие, высокогидрофобные нанокомпозиты на основе фтор-полимера с углеродными нанотрубками // Журн. прикладной химии. 2018. Т. 91. № 10. С. 1462–1467.
Нажипкызы М., Мансуров З.А. Супергидрофобные материалы и покрытия: обзор // Горения и плазмохимия. 2020. № 4. С. 163–180.
Lafuma A., Quere D. Superhydrophobic states // Nat. Mater. 2003. V. 2. P. 457–460.
Mumm F., Van Helvoort A.T.J., Sikorski P. Easy route to superhydrophobic copper–based wire–guided droplet microfluidic systems // ACS Nano. 2009. V. 3. P. 2647–2652.
Rao A.V., Latthe S.S., Nadargi D.Y., Hirashima H., Ganesan V. Preparation of MTMS based transparent superhydrophobic silicafilms by sol–gel method // J. Colloid Interface Sci. 2009. V. 332. P. 484–490.
Xiaoli W., Faxing Z. Surface and mechanical properties of anorganic–inorganic super–hydrophobic coating using modified nano–SiO2 and mixing polyurethane emulsion as raw materials // J. Adhes. Sci. Technol. 2018. V. 32. P. 1809–1821.
Gnanappa A.K., Gogolides E., Evangelista F., Riepen M. Contact line dynamics of a superhydrophobic surface: application for immersion lithography // Microfluid Nanofluidics. 2011. V. 10. P. 1351–1357.
Zhou S.-S., Guan Z.-Sh., Pang Y. Fabrication of Polypropylene Super-Hydrophobic Surface Using PTFE-Coated-Sieves Template via Templating and Splitting Process // Polym. Plast. Technol. Eng. 2012. V. 51. Iss. 1. P. 845–848.
Campos R.B.V., Rocha T.D. da., Wysard Jr. M.M., Camargo Jr. S.A. de S. Superhydrophobic and Low Reflectance Carbon Nanotubes Buckypapers // Materials Research. 2022. V. 25. P. e20220136.
He S., Wei J., Wang H. et al. Stable superhydrophobic surface of hierarchical carbon nanotubes on Si micropillar arrays // Nanoscale Res Lett. 2013. V. 8. P. 412.
Eseev M.K., Goshev A.A., Kapustin S.N., Tsykareva Y.V. Creation of Superhydrophobic Coatings Based on MWCNTs Xerogel // Nanomaterials. 2019. V. 9. P. 1584.
Есеев М.К., Капустин С.Н., Лугвищук Д.С., Мордкович В.З., Лях Н.Л. Сверхгидрофобное покрытие из углеродных наночастиц луковичной структуры // Письма в ЖТФ. 2020. № 22. С. 19.
Kapustin S., Zabolotny S., Eseev M., Tsykareva Y. Double-Layer Superhydrophobic Anti-Icing Coating Based on Carbon Nanoparticles // Crystals. 2022. V. 12. Iss. 10. P. 1501.
Макаров Н.А., Трапезникова Е.С. Способы декорирования углеродных наноструктур с целью связывания с керамической матрицей (обзор) // Успехи в химии и химической технологии. 2020. Т. 34. № 5 (228). С. 92–93.
УНТ серии “Таунит” [Text] / ООО “НаноТехЦентр”; режим доступа: http://www.nanotc.ru/producrions/87-cnm-taunit, свободный; дата обращения 2023-05-19.
Mordkovich V.Z., Lugvishchuk D.S., Mitberg E.B. et al. Formation of concentric shell carbon by homogeneous partial oxidation of methane // Chem. Phys. Lett. 2018. V. 713. P. 242–246.
Shilova O.A., Glebova I.B., Voshchikov V.I., Ugolkov V.L., Dolmatov V.Yu., Komarova K.A., Ivanova A.G. Environmentally friendly antifouling transparent coatings based on sol-gel ‘epoxy/titanium tetrabutoxide’ composition modified with detonation nanodiamond // J. of Advanced Materials and Technologies. 2022. V. 7. Iss. 3. P. 201–218.
Rao K.S., El-Hami K., Kodaki T., Matsushige K., Makino K. A novel method for synthesis of silica nanoparticles // J. of Colloid and Interface Science. 2005. V. 289. Iss. 1. P. 125–131.
Demin V.A., Blank V.D., Karaeva A.R. et al. C60 fullerene decoration of carbon nanotubes // J. Exp. Theor. Phys. 2016. V. 123. P. 985–990.
Jiang G., Liu Z., Hu J. Superhydrophobic and Photothermal PVDF/CNTs Durable Composite Coatings for Passive Anti-Icing/Active De-Icing // Adv. Mater. Interfaces. 2022. V. 9. P. 2101704.
Fan J., Long Z., Wu J. et al. Electrothermal superhydrophobic epoxy nanocomposite coating for anti-icing/deicing // J. Coat. Technol. Res. 2023.
Türk S. Characterization of chitosan/polyethylenimine film layer as a novel anti-fog coating surface // J. Appl. Polym. Sci. 2022. V. 139. Iss. 37. P. e52884.