The effect of crystallization on the Tb3+ emission parameters in a solution of a terbium(III) complex with tetra-1,3-diketone calix[4]arene

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Abstract

An abrupt lengthening (from 295 to 684 μs) of the luminescence decay time of Tb3+ ions in a solution of a terbium(III) complex with tetra-1,3-diketone calix[4]arene in the region of the solution crystallization temperature (212 K) was found. This fact indicates a significant sensitivity of the complex to the structure of the local environment, which can be used both for spectroscopic purposes and for remote monitoring of the phase state of the medium.

About the authors

D.V. Lapaev

Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Author for correspondence.
Email: d_lapaev@mail.ru
Russia, 420029, Kazan

V. G. Nikiforov

Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420029, Kazan

S. N. Sudakova

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center
of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420088, Kazan

S. N. Podyachev

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center
of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420088, Kazan

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Copyright (c) 2023 Д.В. Лапаев, В.Г. Никифоров, С.Н. Судакова, С.Н. Подъячев