Features of the crystal structure of 2D honeycomb frustrated magnet Li 2 Ni 2 TeO 6

A. E. Susloparova; Суслопарова А. Е.; N. S. Fokin; Фокин Н. С.; A. I. Kurbakov; Курбаков А. И.

doi:10.31857/S0367676523702733

Features of the crystal structure of 2D honeycomb frustrated magnet Li₂Ni₂TeO₆

Authors: Susloparova A.E.¹, Fokin N.S.¹, Kurbakov A.I.¹
Affiliations:
1. Konstantinov Petersburg Nuclear Physics Institute, National Research Center “Kurchatov Institute”
Issue: Vol 87, No 11 (2023)
Pages: 1574-1579
Section: Articles
URL: https://ruspoj.com/0367-6765/article/view/654556
DOI: https://doi.org/10.31857/S0367676523702733
EDN: https://elibrary.ru/EIIJKT
ID: 654556

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Using neutron powder diffraction at a temperature of 35 K, slightly above the Neel temperature, the features of the crystal structure of two samples of layered honeycomb oxides of the same stoichiometric composition Li₂Ni₂TeO₆ synthesized from precursors, Na₂Ni₂TeO₆ and K₂Ni₂TeO₆, were determined. They have a similar crystal structure, hexagonal space group P63/mcm, structure type P2, but there is a significant difference in the distances between the layers. Both Li₂Ni₂TeO₆ samples crystallize into the orthorhombic space group Cmca, with minor differences in the unit lattice parameters. If Li₂Ni₂TeO₆ from the potassium precursor is single-phase, then the compound from the sodium precursor contains 16 wt % of an additional phase with the same Li₂Ni₂TeO₆ stoichiometry, but more deformed with monoclinic distortions described by the С2/m space group.

Keywords

neutron powder diffraction, full-profile analysis, quasi-two-dimensional oxide, honeycomb crystal structure

References

Kanyolo G.M., Masese T., Matsubara N. et al. // Chem. Soc. Rev. 2021. V. 50. P. 3990.
Васильев А.Н., Волкова О.С., Зверева А.А., Маркина М.М. Низкоразмерный магнетизм. М.: Физматлит, 2018. 304 с.
Kitaev A. // Ann. Phys. 2006. V. 32. P. 2.
Стрельцов С.В., Хомский Д.И. // УФН. 2017. Т. 187. № 11. С. 1205; Streltsov S.V., Khomskii D.I. // Phys. Usp. 2017. No. 6. P. 1121.
Tokura Y., Kanazawa N. // Chem. Rev. 2021. V. 121. P. 2857.
Bauer A., Pfleiderer C. // Springer Ser. Mater. Sci. 2016. V. 228. P. 1.
Pu Y., Liu Y., Liu D. et al. // Int. J. Hydrogen Energy. 2018. V. 43. P. 17271.
Kadari R., Velchuri R., Sreenu K et al. // Mater. Res. Express. 2016. V. 3. Art. No. 115902.
Evstigneeva M.A., Nalbandyan V.B., Petrenko A.A. et al. // Chem. Mater. 2011. V. 23. P. 1174.
Sau K., Kumar P.P. // J. Phys. Chem. C. 2015. V. 119. P. 18 030.
Masese T., Yoshii K., Yamaguchi Y. et al. // Nature Commun. 2018. V. 9. Art. No. 3823.
Yang Z., Jiang Y., Deng L. et al. // J. Power Sources. 2017. V. 360. P. 319.
Jia Zh., Jiang X., Lin Zh., Xia M. // Dalton Trans. 2018. V. 47. P. 16388.
Kuchugura M.D., Kurbakov A.I., Zvereva E.A. et al. // Dalton Trans. 2019. V. 45. No. 7. P. 17070.
Kurbakov A.I., Korshunov A.N., Podchezertsev S.Y. et al. // Phys. Rev. B. 2017. V. 96. Art. No. 024417.
Stratan M.I., Shukaev I.L., Vasilchikova T.M. et al. // New J. Chem. 2019. V. 43. P. 13545.
Korshunov A., Safiulina I., Kurbakov A. // Phys. Stat. Sol. B. 2020. V. 257. Art. No. 1900232.
Kurbakov A.I., Korshunov A.N., Podchezertsev S.Yu. et al. // J. Alloys Compounds. 2020. V. 820. Art. No. 153 354.
Курбаков А.И., Коршунов А.Н., Пирогов А.Н. и др. // Кристаллография. 2021. Т. 66. № 2. С. 271; Kurbakov A.I., Korshunov A.N., Pirogov A.N. et al. // Crystallography Rep. 2021. V. 66. No. 2. P. 267.
Fouet J.B., Sindzingre P., Lhuillier C. // Eur. Phys. J. B. 2001. V. 20. P. 241.
Li P.H.Y., Bishop R.F., Farnell D.J.J., Campbell C.E. // Phys. Rev. B. 2012. V. 86. Art. No. 144404.
Grundish N.S., Seymour I.D., Henkelman G., Goodenough J.B. // Chem. Mater. 2019. V. 31. P. 9379.
Politaev V.V., Nalbandyan V.B., Petrenko A.A. et al. // J. Solid State Chem. 2010. V. 183. P. 684.
Rodriguez-Carvajal J. // Phys. B. 1993. V. 55. P. 192.
Izumi F., Momma K. // Solid State Phenom. 2007. V. 130. P. 15.
Vasilchikova T., Vasiliev A., Evstigneeva M. et al. // Materials. 2022. V. 15. P. 2563.
Shannon R.D. // Acta Crystallogr. A. 1976. V. 32. P. 751.