Diamond Compact Electrodes with Increased Electroactivity: Anodic Oxidation of Ethylenediaminetetraacetic Acid

Yu. V. Pleskov; Плесков Ю. В.; M. D. Кrotova; Кротова М. Д.; E. A. Еkimov; Екимов Е. А.

doi:10.31857/S0424857023090104

Diamond Compact Electrodes with Increased Electroactivity: Anodic Oxidation of Ethylenediaminetetraacetic Acid

Authors: Pleskov Y.V.¹, Кrotova M.D.¹, Еkimov E.A.²
Affiliations:
1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
2. Vereshchagin Institute for High Pressure Physics, Russian Academy of Sciences
Issue: Vol 59, No 9 (2023)
Pages: 530-535
Section: Articles
URL: https://ruspoj.com/0424-8570/article/view/670941
DOI: https://doi.org/10.31857/S0424857023090104
EDN: https://elibrary.ru/MBLKPO
ID: 670941

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Abstract
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Abstract

The diamond electrodes-compacts with extreme high boron-doping level, added with platinum, were prepared at a pressure of 8―9 GPa and temperature ~2500 К from growth mixtures В–С, Pt–C, and Pt–C–B. They are highly electroactive in the reaction of ethylenediaminetetraacetic acid electrooxidation. The oxidation current is a linear function of the ethylenediaminetetraacetic acid concentration over the 0.001–0.05 g-equ/L range. This system can be basic to an electroanalytical method for the ethylenediaminetetraacetic acid determination.

Keywords

diamond electrode, compact, boron-doping, platinum additive, cyclic voltammetry, ethylenediaminetetraacetic acid, calibration curve

References

Плесков, Ю.В., Кротова, М.Д., Елкин, В.В., Екимов, Е.А. Электрохимическое поведение нового электродного материала-компакта из легированного бором синтетического алмаза. Электрохимия. 2016. Т. 52. С. 3. [Pleskov, Yu.V., Krotova, M.D., Elkin, V.V., and Ekimov, E.A., Electrochemical Behavior of New Electrode Material: Compact of Boron-doped Synthetic Diamond, Russ. J. Electrochem., 2016, vol. 52, p. 1.]
Pleskov, Yu.V., Krotova, M.D., Elkin, V.V., and Ekimov, E.A., Electrochemical Behaviour of Boron-doped Diamond Compacts – a New Electrode Material, Electrochim. Acta, 2016, vol. 201, p. 268.
Ekimov, E.A., Sidorov, V.A., Zoteev, A., Lebed’, Yu., Thompson, J.D., and Stishov, S.M., Diamond compacts, Sci. Technol. Adv. Mater., 2008, vol. 9, p. 044210.
Плесков, Ю.В. Электрохимия алмаза. М.: УРСС, 2003. 101 с. [Pleskov, Yu.V., Electrochemistry of Diamond (in Russian), Moscow: URSS, 2003.]
Electrochemistry of Diamond / Eds. Fujishima, A., Einaga, Y., Rao, T.N., and Tryk, D.A., Tokyo: BKC & Amsterdam: Elsevier, 2005. 586 p.
Synthetic Diamond Films: Preparation, Electrochemistry, Characterization and Applications,/ Eds. Brillas, E. and Martinez-Huitle, C.A., New York: Wiley, 2011. 632 p.
Topics in Applied Physics, vol. 121, Ed. Yang, N., Springer, 2015.
Li, X., Li, H., Li, M., Li, C., Sun, D., Lei, Y., and Yang, B., Preparation of a porous boron-doped diamond/Ta electrode for the electrocatalytic degradation of organic pollutants, Carbon, 2018, vol. 129, p. 543.
Ayres, Z., Newland, J., Newton, M., Mandal, S., Williams, O., and Macpherson, J., Impact of chemical vapour deposition plasma inhomogeneity on the spatial variation of sp2 carbon in boron doped diamond electrodes, Carbon, 2017, vol. 121, p. 434.
Li, J., Bentley, C.L., Tan, S.Y., Mosali, V.S.S., Rahman, M.A., Cobb, S.J., Guo, S., Macpherson, J., Unwin, P., Bond, A., and Zhang, J., Impact of sp2 carbon edge effects on the electron-transfer kinetics of the ferrocene/ferricenium process at a boron-doped diamond electrode in an ionic liquid, J. Phys. Chem. C, 2019, vol. 123, p. 17397.
Kuang, P., Natsui, K., Feng, C., and Einaga, Y., Electrochemical reduction of nitrate on boron-doped diamond electrodes: Effects of surface termination and boron-doping level, Chemosphere, 2020, p. 251.
Notsu, H., Yagi, I., Tatsuma, T., Tryk, D.A., and Fujishima, A., Surface carbonyl groups on oxidized diamond electrodes, J. Electroanal. Chem., 2000, vol. 492, p. 31.
Awada, M., Strojek, J.W., and Swain, G.M., Platinum particles deposited on synthetic boron-doped diamond, J. Electrochem. Soc., 1995, vol. 142. p. L42.
Belghiti, D.K., Zadeh-Habchi, M., Scorsone, E., and Bergonzo, P., Boron doped diamond/metal nanoparticle catalysts hybrid electrode array for the detection of pesticides in tap water. In: Procedia Engineering, Elsevier, 2016, vol. 168, p. 428.
Zribi, B., Dragoe, D., and Scorsone, E., BDD electrodes modified with metal nano-catalysts for coffee discrimination in real samples, Sensors Actuators, B: Chem., 2019, vol. 290, p. 147.
Mei, X., Wei, Q., Long, H., Yu, Z., Deng, Z., Meng, L., Wang, J., Luo, J., Lin, C., Ma, L., Zheng, K., and Hu, N., Long-term stability of Au nanoparticle-anchored porous boron-doped diamond hybrid electrode for enhanced dopamine detection, Electrochim. Acta, 2018, vol. 271, p. 84.
Плесков, Ю.В., Кротова, М.Д., Екимов, Е.А. Компакты из легированного бором синтетического алмаза: электрохимические свойства образцов с предельно высоким уровнем легирования. Электрохимия. 2019. Т. 55. С. 278. [Pleskov, Yu.V., Krotova, M.D., and Ekimov, E.A., The Compacts of Boron-Doped Synthetic Diamond: Electrochemical Properties of Samples with Extremely High Doping Level, Russ. J. Electrochem., 2019, vol. 55, p. 154.]
Плесков, Ю.В., Кротова, М.Д., Хмельницкий, Р.А., Екимов, Е.А. Электроды-компакты из синтетического алмаза c платиной и ее влияние на электрохимическую активность электродов. Электрохимия. 2020. Т. 56. С. 798. [Pleskov, Yu.V., Krotova, M.D., Khmel’nitskii, R.A., and Ekimov, E.A., Russ. J. Electrochem., 2020, vol. 56, p. 724.]
Pleskov, Yu.V., Krotova, M.D., Maslakov, K.I., Sirotinkin, V.P., and Ekimov, E.A., Synthesis of boron-doped carbonado – a new electrode material in C–metal–B growth systems aimed at the lowering of the synthesis temperature without loss of electrochemical activity, J. Solid State Electrochem., 2018, vol. 22, p. 3129.
Ekimov, E.A., Kondrina, K.M., Zibrov, I.P., Lyapin, S.G., Lovygin, M.V., and Kazanskiy, P.R., Iodine-mediated high-pressure high-temperature carbonization of hydrocarbons and synthesis of nanodiamonds, Mater. Res. Bull., 2021, vol. 137, p. 111189.
Angus, J.C., Martin, H.B., Landau, U., Evstefeeva, Y.E., Miller, B., and Vinokur, N., Conducting diamond electrodes: applications in electrochemistry, New Diamond Frontier Carbon Technol., 1999, vol. 9, p. 175.
Плесков, Ю.В., Кротова, М.Д., Ёлкин, В.В., Варнин, В.П., Теремецкая, И.Г. Окисление бензола на аноде из легированного бором алмаза: исследование методом электрохимического импеданса. Электрохимия. 2011. Т. 47. С. 1043. [Pleskov, Yu.V., Krotova, M.D., Elkin, V.V., Varnin, V.P., and Teremetskaya, I.G., Benzene Oxidation at Boron_Doped Diamond Anode: An Electrochemical_Impedance Spectroscopy Study, Russ. J. Electrochem., 2011, vol. 47, p. 973.]