Oxidation of 5-Hydroxumethylfurfural over Supported Pd-Containing Catalysts

K. L. Timofeev; Тимофеев К. Л.; D. P. Morilov; Морилов Д. П.; T. S. Kharlamova; Харламова Т. С.

doi:10.31857/S0453881123040147

Oxidation of 5-Hydroxumethylfurfural over Supported Pd-Containing Catalysts

Authors: Timofeev K.L.¹, Morilov D.P.¹, Kharlamova T.S.¹
Affiliations:
1. National Research Tomsk State University
Issue: Vol 64, No 4 (2023)
Pages: 437-446
Section: 7-я Международная школа-конференция молодых ученых “Катализ: от науки к промышленности”
URL: https://ruspoj.com/0453-8811/article/view/660307
DOI: https://doi.org/10.31857/S0453881123040147
EDN: https://elibrary.ru/RSFDKW
ID: 660307

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Abstract

The results for the oxidation of 5-hydroxymethylfurforol (5-HMF) over Pd/TiO₂ and Pd/ZrO₂ catalysts obtained by impregnation using different heat treatment conditions are presented. The catalysts were studied by XRD, XPS, low-temperature nitrogen adsorption and pulse CO adsorption methods. Catalytic studies were carried out under mild conditions of 5-HMF oxidation: a temperature of 80°C, an oxygen pressure of 5 atm, and the use of NaHCO₃ as a base agent. It is shown that the conditions of temperature treatment significantly affect the formation of the active component over Pd/TiO₂ and Pd/ZrO₂ catalysts, determining dispersion of active component and interaction with the support and, as a consequence, the catalytic properties of the obtained materials.

Keywords

oxidation of 5-hydroxymethylfurforol, 2,5-furandicarboxylic acid, supported palladium catalysts

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