High-Performance Catalysts Based on Hybrid Salicylaldarylimine Complexes of Titanium(IV) Dichloride for the Synthesis of Ultrahigh Molecular Weight Polyethylene with Unentangled Macromolecules

I. V. Oleynik; Олейник И. В.; I. K. Shundrina; Шундрина И. К.; I. I. Oleynik; Олейник И. И.

doi:10.31857/S2308113923700560

High-Performance Catalysts Based on Hybrid Salicylaldarylimine Complexes of Titanium(IV) Dichloride for the Synthesis of Ultrahigh Molecular Weight Polyethylene with Unentangled Macromolecules

Authors: Oleynik I.V.¹, Shundrina I.K.¹, Oleynik I.I.¹
Affiliations:
1. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences
Issue: Vol 65, No 4 (2023)
Pages: 243-253
Section: КАТАЛИЗ
URL: https://ruspoj.com/2308-1139/article/view/650878
DOI: https://doi.org/10.31857/S2308113923700560
EDN: https://elibrary.ru/VAIYCY
ID: 650878

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Abstract

The features of ethylene polymerization in the presence of dichloridobis(salicylaldaryliminato)titanium(IV) complexes containing a 4-allyloxy-2,3,5,6-tetrafluorophenylimino group, namely, {2‑[(4-CH2=CH-CH2O)C6F4N=CH]-6-R1-4-R2-C6H2O}2TiCl2 (R1 = t-Bu, CMe2(Ph); R2 = H, Me, OMe, t-Bu, CMe2(Ph), Cl, Br) in the presence of methylalumoxane, have been studied. All the complexes exhibit high catalytic activity (27.8×106 гПЭ∙мольTi‐ 1∙МПаC2H4-1∙ч‐ 1)) in the temperature range of 10‒60°C and form powdered ultrahigh molecular weight polyethylene (UHMWPE) (M = (4.4–16.0) × 106 g/mol) with a low number of intermolecular entanglements. It has been shown that during polymerization, the complexes are immobilized on UHMWPE macromolecules.

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