Heterometallic manganese(III) coordination polymers with Schiff bases (H2Salpn) and dicyanometallates
- Authors: Kopotkov V.A.1, Zorina L.V.2, Simonov S.V.2, Utenyshev A.N.1, Bozhenko K.V.1
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Affiliations:
- Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
- Osipyan Institute of Solid State Physics, Russian Academy of Sciences
- Issue: Vol 51, No 4 (2025)
- Pages: 255-264
- Section: Articles
- URL: https://ruspoj.com/0132-344X/article/view/679430
- DOI: https://doi.org/10.31857/S0132344X25040059
- EDN: https://elibrary.ru/LPDIAF
- ID: 679430
Cite item
Abstract
Single crystals of the Mn(III) complexes with tetradentate (N2O2) Schiff bases (L) and dicyanometallates [Mn(L)M(CN)2]n, where L = Salpn2– = N,N’-bis(salicylidene)-1,3-diaminopropane, M = M = Ag+ (I), Au+ (II) were obtained for the first time. The molecular structures of I and II were determined by X-ray diffraction (CCDC no. 2351118 (I), 2351119 (II)). It was found that the dicyanometallate anion [M(CN)2]ˉ in the crystal structure of these compounds acts as a bridge binding the Mn(III) moieties with the Schiff base into 1D. Using quantum chemical calculations, the (3, –1) type critical points were found near the C‒H…Ag/Au contact; this attests to the existence of weak hydrogen bonds between these atoms.
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About the authors
V. A. Kopotkov
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: vakopotkov@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
L. V. Zorina
Osipyan Institute of Solid State Physics, Russian Academy of Sciences
Email: vakopotkov@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
S. V. Simonov
Osipyan Institute of Solid State Physics, Russian Academy of Sciences
Email: vakopotkov@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
A. N. Utenyshev
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: vakopotkov@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
K. V. Bozhenko
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: vakopotkov@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
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